Modeling and Comparative Study on Cure Kinetics for CFRP: Autocatalytic vs. Neural Network vs. Angle Information-Enhanced RBF Models. [PDF]
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A Rapid Method for Preparing Transient Thermal Expansion Cracking Agent and Its Thermal Decomposition Kinetics Analysis. [PDF]
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Thermal Conversion of Coal Bottom Ash and Its Recovery Potential for High-Value Products Generation: Kinetic and Thermodynamic Analysis with Adiabatic TD24 Predictions. [PDF]
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How Method Matters: The Impact of Material Characterisation Techniques on Liquid Silicone Rubber Injection Moulding Simulations. [PDF]
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A consideration of errors and accuracy in the isoconversional methods
Thermochimica Acta, 2001Abstract The conventional isoconversional plots, ln β versus 1/ T and ln( β / T 2 ) versus 1/ T , have some errors in calculating the activation energy due to the use of an approximate value of p ( x ). In order to obtain the ‘exact’ value of activation energy of a reaction, an iterative procedure has been established after the ratios, H ( x ...
Masahiro Nakada
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In this paper, fundamentals of the isoconversional methods are summarized and the methods are analyzed from the point of view of their correctness, their applications and the physical meaning of the activation parameters obtained. It is concluded that the activation parameters represent apparent quantities without a mechanistic interpretation.
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Processing of TGA data: Analysis of isoconversional and model fitting methods
Fuel, 2016Abstract Thermogravimetric analysis (TGA) is routinely used to characterize coal. Apart from proximate analysis, TGA data is also used to characterize kinetics of devolatilization and char combustion. Various methods have been proposed to process the TGA data [isoconversional or model free methods such as Friedman method, Kissinger method, Flynn–Wall–
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