Results 91 to 100 of about 110,919 (317)

Addressing the challenges of modeling the scattering from bottlebrush polymers in solution [PDF]

, 2020
Small‐angle scattering measurements of complex macromolecules in solution are used to establish relationships between chemical structure and conformational properties.
Burns, Adam B., Chang, Alice B., Grubbs, Robert H., Martin, Tyler B., Sunday, Daniel F.   +4 more
core  

Identification and quantification of cell gas evolution in rigid polyurethane foams by novel GCMS methodology [PDF]

, 2019
Producción CientíficaThis paper presents a new methodology based on gas chromatography-mass spectrometry (GCMS) in order to separate and quantify the gases presented inside the cells of rigid polyurethane (RPU) foams.
Galakhova, Anastasiia, Riess, Gisbert, Rodríguez Pérez, Miguel Ángel, Santiago Calvo, Mercerdes, Tirado Mediavilla, Josias, Villafañe González, Fernando   +5 more
core   +2 more sources

The Challenging P‐Alkylation of Aromatic Phosphorus Heterocycles and Follow‐Up Reactions

ChemistryEurope, EarlyView.
P‐alkylation of λ3σ2‐phosphinines is hindered by weak nucleophilicity and scarce synthetic access, previously requiring multistep routes or extreme electrophiles. A direct ambient‐condition method is reported using 3,5‐bis(trimethylsilyl)‐phosphinine/B(C6F5)3 with esters or iso(thio)cyanates to generate stable 1‐R‐phosphininium salts.
Samantha Frank, Ádám Horváth, Duy Nguyen, Moritz J. Ernst, Simon Steinhauer, Zoltán Benkő, Christian Müller   +6 more
wiley   +1 more source

Associations Between Glutathione-S-Transferase Genotypes and Bronchial Hyperreactivity Patients With Di-isocyanate Induced Asthma. A Follow-Up Study

Frontiers in Medicine, 2019
Introduction: Di-isocyanates TDI (toluene di-isocyanate), MDI (diphenylmethane di-isocyanate), and HDI (hexamethylene di-isocyanate) are the most common chemicals causing occupational asthma. Di-isocyanate inhalation has been reported to induce oxidative
Jussi Leppilahti, Jussi Leppilahti, Marja-Leena Majuri, Timo Sorsa, Timo Sorsa, Timo Sorsa, Ari Hirvonen, Ari Hirvonen, Päivi Piirilä   +8 more
doaj   +1 more source

Kinetic study of an on-chip isocyanate derivatization reaction by on-line nano-esi ms [PDF]

, 2005
A high-throughput method is presented for the study of reaction kinetics by nano- electrospray ionization mass spectrometry (nano-ESI MS). The reaction of propyl isocyanate (2), benzyl isocyanate (3), and toluene-2,4-diisocyanate (4) with 4-nitro-7 ...
Berg, A. van den, Brivio, M., Karst, U., Liesner, A., Oosterbroek, R.E., Reinhoudt, D.N., Verboom, W.   +6 more
core   +1 more source

(2‐Phosphinophenyl)aluminum Dichloride Complexes as Intramolecular Al/P Frustrated Lewis Pairs for Ketone, Ester, and Imine Activation

Chemistry – A European Journal, EarlyView.
Three 2‐phosphinophenylaluminum dichloride complexes were synthesized and characterized as novel intramolecular FLPs. These FLP systems exhibit high Lewis acidity and effectively activate challenging substrates including aliphatic ketones, imines, and esters. DFT analysis revealed that strain release and Al–P dynamics govern their reactivity. Abstract (
Yoshihiro Nishimoto, Hirotaka Okamoto, Makoto Yasuda   +2 more
wiley   +1 more source

Biobased non-isocyanate poly(carbonate-urethane)s of exceptional strength and flexibility

, 2022
Dominik Wołosz, Paweł G. Parzuchowski
openalex   +1 more source

Learning Strategies from Nature's Blueprint to Cyclic Carbonate Synthesis

ChemSusChem, Volume 18, Issue 6, March 15, 2025.
The development of sustainable synthetic methods for cyclic carbonates draws inspiration from nature, focusing on eco‐friendly processes and renewable resources like CO2 and biomass. This review explore various CO2 activation mechanisms, green chemistry principles, and green catalysts.
Erika Saccullo, Vincenzo Patamia, Chiara Zagni, Antonio Rescifina, Giuseppe Floresta   +4 more
wiley   +1 more source

Curable polyphosphazenes [PDF]

, 1975
Class of polyphosphazene polymers can be cured at moderate temperatures by action of moisture.
Gerber, A. H., Reynard, K. A.
core   +1 more source

Engineering a Stable Solid–Electrolyte Interphase through a Novel Trifluoromethyl‐Free Lithium Salt for Lithium Metal Polymer Batteries

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
The motivation behind the development of the new lithium salt LiDFFSI is to combine the advantages of both LiFSI and LiDFSI salts. LiDFFSI offers high ionic conductivity and enhanced compatibility with aluminum current collectors. Additionally, it promotes the formation of a conductive SEI layer rich in LiF and LiH, which contributes to an extended ...
Lorena García, David Fraile‐Insagurbe, Izaskun Serna, Itziar Aldalur, Leire Meabe, Mikel Arrese‐Igor, Rosalía Cid, Julen Etxabe, Michel Armand, Maria Martinez‐Ibañez   +9 more
wiley   +1 more source