Results 101 to 110 of about 48,553 (267)
Learning Strategies from Nature's Blueprint to Cyclic Carbonate Synthesis
ChemSusChem, Volume 18, Issue 6, March 15, 2025.The development of sustainable synthetic methods for cyclic carbonates draws inspiration from nature, focusing on eco‐friendly processes and renewable resources like CO2 and biomass. This review explore various CO2 activation mechanisms, green chemistry principles, and green catalysts.
Erika Saccullo +4 more
wiley +1 more source
Deep Underground Science and Engineering, EarlyView.A staged three‐dimensional nonlinear soil–structure interaction (SSI) model is established, in which the initial geostress state, tunnel excavation, lining installation, delayed activation of the internal frame, and subsequent surcharge loading are simulated sequentially.
Xinyu Liu +3 more
wiley +1 more source
EcoEnergy, EarlyView.This review summarizes a descriptor‐guided framework for linking theoretical calculations, in situ/operando characterization, synthesis regulation, and application screening in functional materials. Emphasis is placed on dynamic structure–property relationships that enable low‐cost material design with enhanced activity, stability, and environmental ...
Yanyu Jin +9 more
wiley +1 more source
A class of carbonic anhydrase I – selective activators
Journal of Enzyme Inhibition and Medicinal Chemistry, 2017 A series of ureido and bis-ureido derivatives were prepared by reacting histamine with alkyl/aryl-isocyanates or di-isocyanates. The obtained derivatives were assayed as activators of the enzyme carbonic anhydrase (CA, EC 4.2.1.1), due to the fact that ...
Erol Licsandru +4 more
doaj +1 more source
Homochiral Acyl Isocyanates as Diagnostic NMR Probes for the Enantiomeric Purity of Chiral Alcohols
Sultan Qaboos University Journal for Science, 2000 The first reported acyl and sulfonylisocyanates were developed and tested in reactions with chiral alcohols to afford diastereomeric carbamates. NMR analysis of these investigates the chemical shift discrimination that would allow these activated ...
Gregory H. P. Roos, Anthony R. Donovanb
doaj +1 more source
Reaction of acyl isocyanates with 3-formylcamphor
, 2020 Benzoyl and trichloroacetyl isocyanates react with 3-formylcamphor to form only the O-addition, products.
Arbuzov B., Dautova L., Zobova N.
core
Nonthermal Plasma–Enabled Cascade N2 Activation and Electroreduction
EcoEnergy, EarlyView.Integrating plasma‐assisted NOx synthesis with subsequent electrochemical reduction enables the sustainable synthesis of high‐value N‐containing chemicals under ambient conditions. ABSTRACT The development of sustainable nitrogen fixation technologies operating under ambient conditions is critical for reducing the energy intensity and carbon footprint ...
Shijia Li, Wei Gao, Ziyun Wang
wiley +1 more source
CHIMIA, 1992 Adducts obtained by 1,3-dipolar cycloadditions to 2,3-dihydroisothiazol-3-one 1,1-dioxides are inclined to undergo a cheletropic process, by which the newly formed heterocyclic part undergoes aromatization, while SO2 is extruded and an ...
Kaspar F. Burri
doaj +2 more sources
Improvement Upon a Largely Forgotten Method for the Synthesis of N-Alkyl Urazoles
ReactionsN-Alkyl urazoles are important heterocyclic compounds that serve as important precursors to potent N-alkyl 1,2,4-triazoline-3,5-dione electrophiles. Traditional methods for urazole synthesis rely upon the use of toxic isocyanates.
Collin B. Dean +5 more
doaj +1 more source
Isocyanurate Formation During Oxazolidinone Synthesis from Epoxides and Isocyanates Catalysed by a Chromium(Salphen) Complex [PDF]
, 2017 Chromium(salphen) complex 10 is found to be a catalyst for the preparation of oxazolidinones from epoxides and isocyanates. Using the optimal reaction conditions (1.5 mol % of chromium(salphen) complex 10 at 80 °C in toluene for 4 hours), six epoxides ...
Wu, Xiao +5 more
core +1 more source