Results 31 to 40 of about 2,477 (226)

Trace element composition and genesis mechanism of the Fuli Pb-Zn deposit in Yunnan: LA-ICP-MS and in situ S-Pb isotopic constraints

open access: yesFrontiers in Earth Science, 2023
The Fuli Pb-Zn deposit in Yunnan is located in the southeast of the Sichuan-Yunnan-Guizhou (SYG) Pb-Zn metallogenic province in South China. Lead and zinc reserves total approximately 0.3 million tons with an average grade of 18.68% Pb+Zn. The stratiform
Xingyu Liang   +5 more
doaj   +1 more source

Speciation, Structural Refinement, and Distribution of Ti Sites in Titanium Silicalite‐1 From 47/49Ti NMR Crystallography at 28.2 Tesla

open access: yesAngewandte Chemie, EarlyView.
Titanium silicalite‐1 (TS‐1), used in industrial selective oxidation processes, depends on specific, yet still unresolved Ti sites, dispersed within the framework of an MFI‐zeolite. Applying high field (28.2 T) 47/49Ti NMR and 17O NMR spectroscopy for an array of TS‐1 catalysts enables the development of an NMR crystallography protocol and the ...
Christoph J. Kaul   +14 more
wiley   +2 more sources

Advanced oxidation of rhodamine B with hydrogen peroxide over ZnCr layered double hydroxide catalysts

open access: yesJournal of Science: Advanced Materials and Devices, 2017
Zn/Cr layered zinc hydroxide materials with different molar ratios of Cr/Zn have been synthesized through the coprecipitation method at pH of 9.0–9.5. At high Cr/Zn molar ratios of 0.5/1–1/3, the materials possess some layered structure with carbonate ...
Nguyen Tien Thao   +3 more
doaj   +1 more source

Spin‐Dependent Generation of Surface‐Bound Radicals Toward Selective and Long‐Lasting Water Purification

open access: yesAdvanced Functional Materials, EarlyView.
This study develops a novel atomic engineering strategy to fine‐tune the spin state of α‐Fe2O3 catalysts toward a medium‐spin state, thereby modulating peroxymonosulfate activation and selectively yielding surface‐bound radicals. Compared with free radicals, surface‐bound radicals exhibit moderated oxidation potential, extended lifespan, surface ...
Shuyu Wang   +7 more
wiley   +1 more source

Characterization of Chromium Cations in CrAPO-5 Metal Aluminophosphate

open access: yesCrystals
Chromium-substituted aluminophosphate (CrAPO-5) with the AFI crystal structure was prepared for the first time by using microwave conditions at the stage of gel formation and crystallization.
Sergei A. Zubkov   +3 more
doaj   +1 more source

Atomic‐Level Ionic Displacement Polarization Enhanced Piezocatalytic Hydrogen Evolution in Covalent Organic Frameworks

open access: yesAdvanced Functional Materials, EarlyView.
Two isomorphic COFs were synthesized and compared, including an amphoteric COF (SQ‐TAPT) and a neutral COF (PDA‐TAPT). The ionic bonds in SQ‐TAPT introduce more Born effective charges, thereby enhancing its ionic displacement polarization. Experimental and theoretical calculations demonstrated that SQ‐TAPT exhibited higher polarity and stronger ...
Ge Yan   +12 more
wiley   +1 more source

Mixed‐Metal Promotion in a Manganese‐Molybdenum Oxynitride as Catalyst to Integrate C─C and C─N Coupling Reactions for the Direct Synthesis of Acetonitrile from Syngas and Ammonia

open access: yesAdvanced Materials, EarlyView.
Transition metal oxy/carbo‐nitrides show great promise as catalysts for sustainable processes. A Mn‐Mo mixed‐metal oxynitride attains remarkable performance for the direct synthesis of acetonitrile, an important commodity chemical, via sequential C─N and C─C coupling from syngas (C1) and ammonia (N1) feedstocks.
M. Elena Martínez‐Monje   +7 more
wiley   +1 more source

Magnesioferrite synthesized from magnesian-magnetites

open access: yesSemina: Ciências Exatas e Tecnológicas, 2014
Magnesioferrite is an important mineral due to its use in different scientific fields and by the fact that the soil through the action of weathering, can be a source of nutrients essential for plant development by the fact that in the soil.
Marcelo Hidemassa Anami   +1 more
doaj   +1 more source

The Coupling of Ferroelectric Polarization and Oxygen Vacancy Migration Enables Electrically Controlled Thermal Memories

open access: yesAdvanced Materials, EarlyView.
Ferroelectric Hf0.5Zr0.5O2 epitaxial thin films exhibit a non‐volatile, electrically controlled thermal conductivity enabled by the coupling between oxygen vacancy migration, acting as phonon scatterers, and ferroelectric polarization, acting as ion migration valve.
Dídac Barneo   +13 more
wiley   +1 more source

Mineralogical Characteristics and Coloration Mechanism of Yellow-Green Alunite Jade

open access: yesYankuang ceshi, 2020
BACKGROUND As a new kind of jade, yellow-green alunite jade is difficult to positively identify and evaluate due to the lack of research. Yellow-green alunite jade is a new type of jade that has appeared on the market in recent years.
SONG Yan-jun   +5 more
doaj   +1 more source

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