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Isosteric heat of adsorption from thermodynamic Langmuir isotherm
Adsorption, 2021The recently developed thermodynamic Langmuir isotherm model is used to estimate the isosteric heat of adsorption for pure component adsorption. Specifically, pure component adsorption isotherms at different temperatures are first correlated with the thermodynamic Langmuir isotherm model.
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Isosteric Heat of Adsorption: Theory and Experiment
The Journal of Physical Chemistry B, 1999The isosteric heats of adsorption of the components of a gas mixture are critical variables for design of adsorbers for gas separation. They can be unambiguously defined by the Gibbsian Surface Excess (GSE) model of multicomponent adsorption. These variables can be experimentally measured by multicomponent differential calorimetry (MDC) and directly ...
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