The biosynthetic mechanism of novel natural tetramic acid S‐TeA in Alternaria alternata is elucidated. Threonine acts as a precursor for 2‐amino‐3‐methylhexanoic acid (AMHA) synthesis via eight key enzymes from the branched‐chain amino acid biosynthetic pathway in the mitochondrion, wherein three unique enzymes (IPMS, IPMDH, and ISMD) play critical ...
He Wang+9 more
wiley +1 more source
Isotope Discrimination Effects in the Metabolism of Tritiated Glucose
Joseph Katz+2 more
openalex +1 more source
Effects of thyrotropin upon thyroidal iodide; studies using thyroid venous cannulation and two radioiodine isotopes. [PDF]
G H Isaacs+2 more
openalex +1 more source
In people with overweight or obesity, regular exercise even without weight loss or vitamin D supplementation completely prevents the usual winter decline in the vitamin D metabolite that maintains health at a cellular level, 1,25(OH)2D3, and ameliorates the decline in the vitamin D status marker 25(OH)D.
Oliver J. Perkin+11 more
wiley +1 more source
Deuterium Isotope Effects on Acid-Base Equilibrium of Organic Compounds. [PDF]
Liu M, Gao J.
europepmc +1 more source
Solvent Deuterium Isotope Effects on Acid-Base Reactions. Part II. Variation of the First and Second Acidity Constants of Carbonic and Sulfurous Acids in Mixtures of Light and Heavy Water. [PDF]
Pentti Salomaa+7 more
openalex +1 more source
Isotope effects on L-H threshold and confinement in tokamak plasmas
C. Maggi+26 more
semanticscholar +1 more source
A General Strategy for C(sp3)─H Bond Etherification via Quinoline Derivative‐Mediated Electrolysis
A quinoline‐based mediator is introduced for the electrochemical etherification of C(sp3)─H bonds, enabling the process with minimal dependence on substrate electronic properties. The reaction demonstrates compatibility with various C─H bonds, including tertiary benzylic C─H bonds and unactivated C(sp3)─H bonds.
Yousen Xu+4 more
wiley +1 more source
Revised microbial and photochemical triple-oxygen isotope effects improve marine gross oxygen production estimates. [PDF]
Sutherland KM+4 more
europepmc +1 more source
The nitrogen cycle: A review of isotope effects and isotope modeling approaches
T. Denk+7 more
semanticscholar +1 more source