Results 11 to 20 of about 12,068,996 (359)

Kinetic nitrogen isotope effects of 18 amino acids degradation during burning processes [PDF]

open access: yesScientific Reports
Understanding the nitrogen isotopic variations of individual amino acids (AAs) is essential for utilizing the nitrogen isotope values of individual amino acids (δ15N-AA) as source indicators to identify proteinaceous matter originating from biomass ...
Ren-Guo Zhu   +7 more
doaj   +2 more sources

Ideas and perspectives: the same carbon behaves like different elements – an insight into position-specific isotope distributions [PDF]

open access: yesBiogeosciences, 2020
It is expected that information on the source, reaction pathway, and reaction kinetics of an organic compound can be obtained from its position-specific isotope compositions or intramolecular isotope distribution (Intra-ID).
Y. He   +5 more
doaj   +1 more source

Sulfate triple-oxygen-isotope evidence confirming oceanic oxygenation 570 million years ago

open access: yesNature Communications, 2023
The largest negative inorganic carbon isotope excursion in Earth’s history, namely the Ediacaran Shuram Excursion (SE), closely followed by early animal radiation, has been widely interpreted as a consequence of oceanic oxidation.
Haiyang Wang   +5 more
doaj   +1 more source

Poly(3-Hydroxybutyrate) Biosynthesis from [U-13C6]D-Glucose by Ralstonia eutropha NCIMB 11599 and Recombinant Escherichia coli

open access: yesMicrobiology Research, 2023
The use of stable isotope-labeled polymers in in situ biodegradation tests provides detailed information on the degradation process. As isotope-labeled raw chemicals are generally expensive, it is desirable to prepare polymer samples with high production
Ramamoorthi M. Sivashankari   +2 more
doaj   +1 more source

Isotope effects in liquid water via deep potential molecular dynamics [PDF]

open access: yesMolecular Physics, 2019
A comprehensive microscopic understanding of ambient liquid water is a major challenge for ab initio simulations as it simultaneously requires an accurate quantum mechanical description of the underlying potential energy surface (PES) as well as ...
Hsin-Yu Ko   +6 more
semanticscholar   +1 more source

Isotope Effects and the Atmosphere

open access: yesAnnual Review of Physical Chemistry, 2023
Chemical physics plays a large role in determining the isotopic compositions of gases in Earth's atmosphere, which in turn provide fundamental insights into the sources, sinks, and transformations of atmospheric gases and particulates and their influence on climate.
Julia M, Carlstad, Kristie A, Boering
openaire   +2 more sources

An Isotope Effect in Photosynthesis [PDF]

open access: yesThe Journal of Chemical Physics, 1949
In the course of some kinetic studies on photosynthesis of barley seedlings, it has been found that plants utilize C{sup 12}O{sub 2} faster than C{sup 14}O{sub 2}. The plants were placed in a closed system containing an infra-red absorption-cell for the analysis of total CO{sub 2} and an ionization chamber for the determination of C{sup 14}O{sub 2} in ...
Weigl, John W, Calvin, M
openaire   +5 more sources

Isotope and Spin Effects Induced by Compression of Paramagnetic Molecules

open access: yesPhyschem, 2022
The zero-point energies (ZPEs) of paramagnetic molecules, free and compressed in a C59N paramagnetic cage, were computed. The excess of energy acquired by molecules under compression depended on the deuterium and tritium isotopes which ranged from 6–8 ...
Irene Barashkova   +3 more
doaj   +1 more source

Kinetic Isotope Effects: Interpretation and Prediction Using Degrees of Rate Control

open access: yesACS Catalysis, 2020
Kinetic isotope effects (KIEs) have been used for decades in catalysis research as a tool for clarifying reaction mechanisms.
Zhongtian Mao, C. Campbell
semanticscholar   +1 more source

Quantifying the nitrogen isotope effects during photochemical equilibrium between NO and NO2: implications for δ15N in tropospheric reactive nitrogen

open access: yes, 2020
. Nitrogen isotope fractionations between nitrogen oxides (NO and NO2 ) play a significant role in determining the nitrogen isotopic compositions ( δ15N ) of atmospheric reactive nitrogen.
Jianghanyang Li   +4 more
semanticscholar   +1 more source

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