Ligand effects, solvent cooperation, and large kinetic solvent deuterium isotope effects in gold(I)-catalyzed intramolecular alkene hydroamination. [PDF]
Lan R, Yager B, Jee Y, Day CS, Jones AC.
europepmc +1 more source
Sulfur Isotope Effects. I. The Isotopic Exchange Coefficient for the Sulfur Isotopes 34S-32S in the System SO2g-HSO3-aq at 25, 35, and 45 degrees C. [PDF]
Trygve E. Eriksen+5 more
openalex +1 more source
Multi‐Omics and ‐Organ Insights into Energy Metabolic Adaptations in Early Sepsis Onset
This study shows that patients at risk of sepsis have a distinct metabolite and lipid signature, including serine and aminoadipic acid, in their serum before clinical diagnosis. A mouse model of sepsis with a compatible serum signature reveals underlying metabolic changes, including mitochondrial adaptation, altered serine‐dependent purine metabolism ...
Lin‐Lin Xu+9 more
wiley +1 more source
Structural Effects on the Temperature Dependence of Hydride Kinetic Isotope Effects of the NADH/NAD+ Model Reactions in Acetonitrile: Charge-Transfer Complex Tightness Is a Key. [PDF]
Beach A+5 more
europepmc +1 more source
Solvent Deuterium Oxide Isotope Effects on the Reactions of Organophosphorylated Acetylcholinesterase. [PDF]
Rosenberry TL.
europepmc +1 more source
Deuterium isotope effects and assignment of 13C chemical shifts in spectra of methyl octadecanoate and the sixteen isomeric oxooctadecanoates [PDF]
A. P. Tulloch
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Magnesium‐Mediated Electrochemical Synthesis of Ammonia
This study demonstrates a lithium‐free, magnesium‐mediated electrochemical process for converting nitrogen (N₂) to ammonia (NH₃) under mild conditions. Using abundant materials, the system achieves ≈27% Faradaic efficiency at lower voltages than Li‐ and Ca‐mediated systems.
Ishita Goyal+5 more
wiley +1 more source
Isotope effects in nucleophilic substitution reactions. III. The effect of changing the leaving group on transition state structure in SN2 reactions [PDF]
Kenneth Charles Westaway+1 more
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The Immune Microenvironment: New Therapeutic Implications in Organ Fibrosis
This review summarizes recent advances in understanding the immune microenvironment's role in fibrosis, focusing on phenotypic/functional alterations of immune cells and their dynamic interactions with other cellular constituents within tissues. The authors further explore therapeutic opportunities and challenges in targeting immune microenvironment ...
Xiangqi Chen+6 more
wiley +1 more source