Results 301 to 310 of about 12,174,017 (385)

Observation of Edge‐Confined Acoustic Hyperbolic Polaritons in van der Waals Materials

open access: yesAdvanced Science, EarlyView.
This work demonstrates a new type of light wave—edge‐confined acoustic hyperbolic polaritons—in hexagonal boron nitride on gold. These waves travel along crystal edges with nanoscale confinement and strongly interact with molecular vibrations, enabling highly sensitive detection of tiny molecular layers.
Tianning Zhang   +4 more
wiley   +1 more source

Computation‐Guided Dual‐Site Electrocatalysts for Record‐Performance Nitrite‐to‐Ammonia Conversion

open access: yesAdvanced Science, EarlyView.
Designing Cu doped ZnO catalysts for NO2RR via first principles calculation and boosting electrocatalytic nitrite reduction through Cu‐ZnO synergistic deoxygenation, hydrogenation, and NH3 desorption. Cu doping elevates the d‐band center of Zn, strengthening *NO2 binding and deoxygenation, while ZnO sites regulate water adsorption and dissociation ...
Hui Zhang   +15 more
wiley   +1 more source

Giant Isotope Effect in Metal–Organic Frameworks Boosts Unprecedented Photo‐ and Radio‐Luminescence Enhancement

open access: yesAdvanced Science, EarlyView.
Deuterated MOFs in this work exhibited unprecedented giant luminescence isotope effect via O─H oscillator suppression, achieving maximal solid‐state materials emission enhancement. This yields significantly improved X‐ray detection sensitivity and imaging resolution, marking the first integration of MOFs with isotopic luminescence and opening new ...
Junhao Lu   +16 more
wiley   +1 more source

Structural Basis of the Membrane Association by the Conserved RocS Membrane‐Targeting Sequence in Streptococcus

open access: yesAdvanced Science, EarlyView.
Chromosome segregation in Streptococcus pneumoniae depends on RocS, a bitopic protein whose membrane‐anchoring mechanisms were unclear. Using NMR and AFM, this study reveals that the widely conserved RocS anchor binds to membranes via a conserved kink‐helix motif which inserts into lipid nanodomains.
Ana Álvarez‐Mena   +11 more
wiley   +1 more source

Electronic Interaction at Cu–O–Ni Heterointerface Promotes Electrocatalytic Nitrate Reduction to Ammonia and Zinc‐Nitrate Battery

open access: yesAdvanced Science, EarlyView.
The strong Cu–O–Ni electronic interaction in the heterostructured catalyst can enhance the effective adsorption of NO3− and accelerate the in situ hydrolysis dissociation of the hydrogenation step. The Zn‐NO3 hybrid battery assembled with this catalyst achieves an open‐circuit voltage of 1.45 V, a peak power density of 6.47 mW cm−2, and can ...
Taozhi Lv   +5 more
wiley   +1 more source

Molecular Weaving of Mixed‐Addenda Polyoxometalates into MOF Nanochannels as Electron‐Buffering Reservoirs for Enhanced Nitrate‐to‐Ammonia Electrocatalysis

open access: yesAdvanced Science, EarlyView.
Synergistic interaction between P2W17V1 and FeMOF owing to its efficient proton/electron transfer affording high yield and Faradaic efficiency in electrocatalytic nitrate reduction to ammonia. ABSTRACT Electrochemical conversion of nitrate pollutants into value‐added ammonia (e‐NO3RA) offers a sustainable pathway for nitrogen valorization, yet hinges ...
Gang Li   +3 more
wiley   +1 more source

Photocatalytic Asymmetric C‐C Coupling for CO2 Reduction on Cu‐Zn Bimetallic Catalysts with Dipole‐Limiting Effects

open access: yesAdvanced Science, EarlyView.
Asymmetric Cu–Zn dual sites on EDTA‐grafted Ti‐MOF amplify the dipole‐limiting domain field (DLDF), facilitating C–C coupling. This strategy yields an exceptional C2H4 production rate of 308.72 µmol g−1 h−1 with 98.4% electron selectivity in photocatalytic CO2 reduction, highlighting the potential of asymmetric site engineering and local field ...
Peidong Ma   +8 more
wiley   +1 more source

Intramolecular Synergy of CO2 Activation and H Spillover on Heteronuclear Dual‐Metal Phthalocyanine Assemblies for Selective CO2 Photoreduction

open access: yesAdvanced Science, EarlyView.
The CuNiPc/BiVO4 heterojunction is designed and synthesized for selective CO2 photoreduction. The cascade interfacial Z‐scheme charge transfer and the intramolecular synergy of Cu–Ni dual sites on CO2 activation and H spillover contribute to the high photocatalytic performance and selectivity. ABSTRACT Solar‐driven CO2 conversion holds great promise in
Ye Liu   +10 more
wiley   +1 more source

Synergetic Relay Between Atomic Hydrogen and Chlorine Radicals Enables Efficient Nitrate‐to‐Nitrogen Gas Conversion

open access: yesAdvanced Science, EarlyView.
Using photoelectrochemical (PEC) deep denitrification technology, a novel synergistic reduction‐oxidation process enables efficient conversion of nitrate (NO3−) to nitrogen (N2), while suppressing key intermediate ammonium (NH4+) and toxic nitrite (NO2−) accumulation.
Yongjie Wang   +11 more
wiley   +1 more source

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