Results 231 to 240 of about 27,362 (303)

Dinuclear Copper(I) Complexes Featuring Metal–Metal Interactions and a μ2‐Bridging Phosphane With Additional Olefinic Binding Sites

Chemistry – A European Journal, EarlyView.
A Cu2P triangle captured in a tetrapodal phosphane tris(olefin) ligand, where all binding forces are weak apart from the Cu─P interaction. ABSTRACT The molecule Ptrop3 contains in each trop unit (trop = dibenzo[a,d]cyclohepten‐5‐yl) a rigid central seven‐membered ring with an olefinic binding site making Ptrop3 potentially a tetradentate ligand ...
Zhongshu Li, Daniel Himmelbauer, Jan Oswald, Michael Wörle, René Verel, Zoltán Benkő, Hansjörg Grützmacher   +6 more
wiley   +1 more source

The Role of Iron‐Hyponitrite Intermediates in Biology and Insights From Synthetic Model Complexes

Chemistry – A European Journal, EarlyView.
Despite the difference in active site architecture, NO reduction by different NOR enzymes is expected to be linked by a common intermediate: hyponitrite (N2O22−). However, experimentally, very little is known about the coordination chemistry of iron with hyponitrite and the expected Fe‐hyponitrite intermediates.
Michael O. Lengel, Nicolai Lehnert
wiley   +1 more source

Oxidative Generation and Reactivity of the Cyclopropyl Radical From a Martin Silicate

Chemistry – A European Journal, EarlyView.
A photoredox strategy employing Martin silicates enables the oxidative generation and controlled capture of cyclopropyl radicals, including the naked one, long considered challenging intermediates. The method affords functionalized cyclopropanes through both Giese‐type additions and dual nickel/photoredox C(sp3)−C(sp2) cross‐couplings.
Amal Lakhal, Alexandre Millanvois, Louis Fensterbank, Cyril Ollivier   +3 more
wiley   +1 more source

Recent Zeolite Modifications in Bifunctional Catalysts for Carbon Dioxide Hydrogenation to Aromatics: A Minireview†

Chinese Journal of Chemistry, EarlyView.
Thermocatalytic hydrogenation of CO2 to aromatic hydrocarbons represents a sustainable route for high‐value CO2 utilization. Bifunctional catalysts combining metal/metal oxide components with acidic zeolites enable the direct synthesis of BTX aromatics.
Weilin Wang, Qinghua Li, Tsz‐Woon Benedict Lo, Ka‐Fu Yung, Cong Lin   +4 more
wiley   +1 more source

Linear and Two‐Dimensional Infrared Spectroscopy of the Multifunctional Vibrational Probe, 3‐(4‐Azidophenyl) Propiolonitrile. Deperturbing a Fermi Triad by Isotopic Substitution

ChemPhysChem, Volume 26, Issue 6, March 15, 2025.
Linear infrared spectroscopy combined with isotope labeling and density functional theory unravels the origin of a Fermi triad in a multifunctional vibrational chromophore. Ultrafast 2DIR‐spectroscopy reports directly on the dynamics and the intramolecular vibrational energy flow pathways in the isotopically deperturbed system. Abstract Infrared probes
Claudia Gräve, Jörg Lindner, Stefan Flesch, Luis I. Domenianni, Peter Vöhringer   +4 more
wiley   +1 more source

Investigations Into the Metabolism and Elimination of Tesofensine in Human Urine

Drug Testing and Analysis, EarlyView.
This study investigated tesofensine metabolism and urinary elimination after a single 483 μg intake via a dietary supplement. In six volunteers, urine was collected up to 659 h. LC‐HRMS/MS identified four tentative metabolites; maximum urinary concentrations reached 4 ng/mL within 4–48 h.
O. Krug, A. Thomas, M. Thevis
wiley   +1 more source

Polyoxometalates in Photocatalytic CO2 Reduction: Multielectron Redox Regulation Across Molecular and Hybrid Architectures

EcoEnergy, EarlyView.
This review focuses on multielectron redox regulation across molecular and hybrid architectures for photocatalytic CO2 reduction, covering intrinsic POM photocatalysts, photosensitizer‐assisted assemblies, POM–metal–organic complexes, and POM‐integrated semiconductors and MOF/COF heterostructures to link structural motifs with charge transport, product
Bonan Li, Xiaowen Ruan, Sai Kishore Ravi
wiley   +1 more source

Synergistic Engineering of Oxygen Vacancies and Topological Surface States in Bi2Te3/TiO2‐X Heterostructures for Highly Efficient Photothermal‐Driven CO2 Photoreduction

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Integrating the topological insulator Bi2Te3 with oxygen‐deficient TiO2‐X creates a synergistic platform for full‐spectrum CO2 reduction, achieving high‐selectivity C2+ production via enhanced photothermal catalysis and tailored charge dynamics.
Bingke Zhang, Chenchen Zhao, Jing Qiao, Changcun Li, Yang Wang, Xingshuo Liu, Dongbo Wang, Gang Liu, Zhao Qian, Rajeev Ahuja, Jinzhong Wang, Degang Zhao   +11 more
wiley   +1 more source

Support‐Driven Hydrogen Migration Enhances Ammonia Decomposition in Direct Ammonia Protonic Ceramic Fuel Cells

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
Enhanced hydrogen species migration enabled by FN/BZY catalyst mitigates intermediate accumulation and improves DA‐PCFC performance during ammonia decomposition. Ammonia, with its high hydrogen density and carbon‐free nature, serves as ideal fuel for direct ammonia protonic ceramic fuel cells (DA‐PCFCs).
Meijuan Fei, Shuai Wang, Zhaohui Cai, Dongliang Liu, Cheng Huang, Xixi Wang, Jie Miao, Huangang Shi, Chuan Zhou, Wei Zhou   +9 more
wiley   +1 more source

Solar Fuels Via Methane Valorization: Thermochemical Pathways, Unified Metrics, and Techno‐Economic Perspectives

ENERGY &ENVIRONMENTAL MATERIALS, EarlyView.
A first‐of‐its‐kind review benchmarks three solar methane valorization pathways with unified performance metrics for clean fuel production. Meeting global climate targets and sustainable energy demands requires carbon‐neutral fuels and innovative conversion pathways.
Muhammad Abdulmoez, Amjad Othman, Majid Linjawi, Amro Al‐Qutub   +3 more
wiley   +1 more source