Results 181 to 190 of about 101,472 (247)

The Newly Discovered Pathway for Oxygen Evolution Reaction: In‐Situ/Operando Characterization Techniques for Catalyst Development

Carbon Energy, EarlyView.
This study introduces a newly discovered oxide path mechanism (OPM) for the oxygen evolution reaction (OER), emphasizing the role of in‐situ and operando characterization techniques in unraveling catalyst behavior under realistic conditions. The integration of advanced spectroscopic methods provides new mechanistic insights for the design of highly ...
Rabia Khalid, Muhammad Tahir, Muhammad Umar, Pin Fang, Yujing Li   +4 more
wiley   +1 more source

An All‐in‐One Lignin‐Based Artificial Thylakoid Nanovesicle Via In‐Situ Confined Growth Strategy for High‐Efficient and Selectivity CO2 Photoreduction

Carbon Energy, EarlyView.
The low light/CO2 capture and slow dynamic transfer of photogenerated electrons hamper photocatalysts’ high activity and selectivity. Inspired by the chloroplast's photosynthesis mechanism, an all‐in‐one lignin‐based artificial thylakoid nanovesicle (AiO‐L‐ATN) is constructed using a confined growth strategy of lignin molecules. The performance of such
Hang Wang, Ganmao Su, Xianxian Lin, Yan Qing, Yiqiang Wu, Fuxiang Chu, Fuquan Xiong   +6 more
wiley   +1 more source

A “Two‐Pronged” Strategy Boosting the Activity and Stability of Nickel–Iron Catalysts Toward Anion Exchange Membrane Water Electrolysis

Carbon Energy, EarlyView.
A “two‐pronged” strategy has been developed to construct a substrate‐strengthened, organophosphorus‐protected nickel‐iron electrode for efficient and robust OER electrocatalysis. Owing to the reinforced catalyst–substrate interaction and minimized active site loss by organophosphorus protection, the integrated electrode serves as an robust and ...
Yansong Zhou, Tianze Xu, Tianyu Qiu, Zhitong Wang, Zhuming Mao, Yanjing Liu, Bingqian Pang, Yina Guo, Tianyang Liu, Xianlong Zhou, Qiongrong Ou, Xinlong Tian, Shuyu Zhang   +12 more
wiley   +1 more source

Enhancing the d–Electrocatalytic Activity of MXene Through Defect Engineering

Carbon Energy, EarlyView.
Applications of MXene. ABSTRACT Due to their versatile and tunable surface and bulk chemistry, MXenes have great potential as electrocatalysts for batteries and supercapacitors. When compared with other electrocatalytic processes, in electrocatalytic reactions, MXenes could improve ion diffusion and charge transfer by either providing functional groups
Chenxue Wang, Zixin Wang, Wen Lei, Haijun Zhang, Yuhua Wang   +4 more
wiley   +1 more source

Regulating Defect‐Coordinated Single‐Iron‐Atom Catalysts for Efficient Nitrate Reduction Reactions

Carbon Energy, EarlyView.
This figure illustrates the ball‐and‐stick model of an asymmetric monatomic Fe─N2 catalyst and its catalytic process for converting nitrate to ammonia. Shown are the adsorption configurations of precursors and intermediates (NO3− → NO2− → NO → NH2OH → NH3) on the catalyst surface, where brown represents iron atoms, red represents oxygen atoms, dark ...
Xia Ma, Haoying Han, Zhonghui Yang, Hua Li, Xinyu Yan, Jiakang Guo, Chen Chen, Xiaorui Jiao, Yajun Xiang, Gang Wang, Yanwei Yang, Fengjuan Chen, Liang Huang   +12 more
wiley   +1 more source

Interfacial Ru–O–W Orbital Coupling Enables Lattice Oxygen Stabilization for Enhanced Acidic OER

Carbon Energy, EarlyView.
A RuO2/WO3 electrocatalyst with strong interfacial Ru–O–W bonds exhibits optimized Ru–O interactions, enhancing intrinsic activity and stability for acidic OER. The WO3 support modulates the electronic structure of RuO2 and promotes oxo‐intermediate deprotonation, delivering a low overpotential of 203 mV at 10 mA cm−2 and sustained operation beyond 200 
Tongzhou Wang, Shoujian Duan, Junyu Pan, Jihong Li, Li Shao, Lei Shi, Yuhan Sun, Jingming Ran, Huaiyu Shao, Yida Deng   +9 more
wiley   +1 more source

Shedding Light on Synthetic Autocatalysis: From Conventional Closed‐Shell Chemistries to Overlooked Open‐Shell Occurrences

Chemistry – A European Journal, EarlyView.
Why add another catalyst when the product itself holds the power to catalyze its own formation? Autocatalysis in synthetic chemistry enhances reaction efficiency and uncovers novel catalytic behavior across both closed‐shell and open‐shell systems, expanding reactivity and enabling innovative design strategies.
Jaspreet Kaur, Joshua P. Barham
wiley   +1 more source

Copper(II), a Peculiar Metal Ion for Complexation with Monensin A Ionophore

Chemistry – A European Journal, EarlyView.
Copper(II) forms three chiral and EPR‐active complexes with monensinate A in methanol. Beside the bis [CuL2] and mono [CuL]+ species, the new dinuclear construct [Cu2L]3+ exhibits an [ML]+‐type and a metal salt‐type copper(II) centers weakly bound to each other through counter ion(s) and thus, being magnetically independent.
Máté Levente Kis, Bálint Hajdu, Tamás Jakusch, Zoltán Kele, Petar Dorkov, Rositsa Kukeva, Ivayla Pantcheva, Béla Gyurcsik   +7 more
wiley   +1 more source

Regio‐ and Diastereoselective C–C Silylation of Cyclopropyl Acetates Harnessing Fluorinated Poly(pyridyl)Borate Rhodium Catalysts

Chemistry – A European Journal, EarlyView.
Fluorinated poly(pyridyl)borates have been utilized to stabilize rhodium‐diene complexes and as supporting ligands in rhodium‐catalyzed redox‐neutral C–C silylation of cyclopropyl acetates, producing silicon‐containing heterocyclic products, dioxasilolanes.
Vo Quang Huy Phan, Suman Das Adhikary, Junha Jeon, H. V. Rasika Dias   +3 more
wiley   +1 more source

Investigations Into the Human Metabolism of Trestolone (7α‐Methyl‐19‐Nortestosterone)

Drug Testing and Analysis, EarlyView.
As the known metabolites of 7α‐methyl‐19‐nortestosterone (MENT), M1 and M2, suffer from chromatographic issues under routine doping control conditions, the human metabolism of MENT was reinvestigated. From the numerous new metabolites detected, especially, M5 and M10 were identified as the most promising candidates to be implemented into routine ...
Thomas Piper, Gregor Fusshöller, Mario Thevis   +2 more
wiley   +1 more source