Measurement of Stable Carbon Isotope Ratio of Volatile Organic Compounds Using Thermal Desorption-Gas Chromatography-Combustion-Isotope Ratio Mass Spectrometry. [PDF]
Yuhong L, Xihuang L, Cifu L, Xijie Y.
europepmc +1 more source
A photochemical platform enables β–β coupling of cyclopropyl silyl ethers with electron‐deficient alkenes. The resulting adducts serve as entry points into annulative and radical–polar crossover pathways, providing rapid access to fused, bridged, and spirocyclic architectures, including late‐stage scaffold diversification to diterpene‐like carbocyclic ...
Jacop Rydén +5 more
wiley +2 more sources
Heart-Cutting Two-Dimensional Liquid Chromatography-Isotope Ratio Mass Spectrometry for Compound-Specific δ<sup>13</sup>C Analysis of Water-Soluble B Vitamins in Complex Supplement Matrices. [PDF]
Rockel SP +3 more
europepmc +1 more source
Borylcyclopropanes: Synthetic Strategies and Applications
Borylcyclopropanes (cyclopropanes bearing a boron substituent) sit at the intersection of two privileged frameworks in synthesis. This review provides the first exhaustive survey of their chemistry, spanning metal–carbene, nucleophilic cyclization, radical, hydroboration, and C─H activation routes, and documenting applications in medicinal chemistry ...
Aiza A. Butt, Joseph M. Ready
wiley +2 more sources
Thermodiffusion and thermo-osmosis in thin membranes with slit pores. [PDF]
Hafskjold B, Kjelstrup S.
europepmc +1 more source
A heterogeneous photocatalytic system has been developed that enables the dehydrogenative decarbonylation of primary alcohols under visible light using highly dispersed oxidic iron sites supported on aryl‐modified graphitic carbon nitride (Fe@f–gC3N4).
Jun Hu +11 more
wiley +2 more sources
Toward diagnostically relevant isotope-ratio biomarkers: what does MC-ICP-MS still need for standardized measurements? [PDF]
Ramirez DA, Meermann B.
europepmc +1 more source
We report selective five‐coordinate passivation of phosphorene via P═C double bonds using a facile one‐step photochemical reaction via carbene addition. The ambient stability of functionalized phosphorene has been substantially improved compared to the pristine phosphorene.
He Zhang +12 more
wiley +2 more sources
Electrochemical fractionation of stable sulfur isotopes in a rechargeable lithium-sulfur battery: a revisit from the law of mass conservation. [PDF]
Zhu YH, Xin S.
europepmc +1 more source
NMR screening is a powerful method for hit detection in drug‐discovery. We designed and validated the OpenFL600 19F$^{19}{\rm F}$ NMR library to probe diverse targets, including RNA, GPCRs, kinases, and proteases. This library yields target‐specific ligands without generating promiscuous binders.
Simon H. Rüdisser +16 more
wiley +2 more sources

