Results 141 to 150 of about 173,935 (289)

Fused Ring Engineering Induced Topology Control in Covalent Organic Frameworks: Unlocking Promoted Photocatalytic H2O2 Production and Selective Methane Oxidation

Angewandte Chemie, EarlyView.
By modulating the topological structures of two N‐heterocycle‐based covalent organic frameworks, Phen‐TTA with a kgd‐v topology exhibits narrower optical bandgap, lower exciton binding energy, and faster charge‐carrier kinetics compared to O‐TTA with an hcb topology.
Lei Wang, Zhipeng Xie, Xinyi Zeng, Hetao Xu, Mingyue Wang, Jie Yang, Chao Lin, Wandong Xing, Zhengxiao Guo, Xiong Chen   +9 more
wiley   +2 more sources

Safety of Sodium‐Ion Batteries: Evaluation and Perspective from Component Materials to Cells, Modules, and Packs

Advanced Energy Materials, EarlyView.
This review provides a bottom‐up evaluation of sodium‐ion battery safety, linking material degradation mechanisms, cell engineering parameters, and module/pack assembly. It emphasizes that understanding intrinsic material stability and establishing coordinated engineering control across hierarchical levels are vital for preventing degradation coupling ...
Won‐Gwang Lim, Seoa Kim, Erik A. Wu, Darren H. S. Tan, Shawn Peng, Xiaolin Li   +5 more
wiley   +1 more source

Emerging Materials and Future Strategies for Solid Oxide Electrochemical Cells

Advanced Energy Materials, EarlyView.
Solid oxide electrochemical cells operate under strongly coupled electrochemical and thermodynamic conditions, where performance is constrained by interactions among crystal structure, defect chemistry, and interfacial evolution. This review, based on a structure‐defect‐property‐durability framework, reveals the roles of lattice symmetry and defect ...
Qiuchun Lu, Yufei Zhang, Han Zhao, Pooi See Lee, Daniel H.C. Chua   +4 more
wiley   +1 more source

Deprotonative C(sp3)/C(sp2)–H (Multi)Silylation of (Hetero)Arenes Mediated by NaTMP

Angewandte Chemie, EarlyView.
An operationally simple protocol using a strongly basic sodium amide in combination with sterically emcumbered silicon electrophiles enables the deprotonative C–H (multi)silylation of a myriad of (hetero)arenes. Mechanistic investigations highlight the pivotal role of steric and coordination effects in controlling the regioselectivity and efficiency of
David Sánchez‐Roa, Sophia Belrhomari, Ana McGinley, Clevin Anto Liju, Manting Mu, Max García‐Melchor, Eva Hevia   +6 more
wiley   +2 more sources

Main‐Chain Ion‐Pair Polybenzimidazole Membranes Enabling Reduced‐Temperature HT‐PEMFC Operation (Down to 120°C)

Advanced Energy Materials, EarlyView.
Embedding imidazolium‐biphosphate ion pairs directly into the polybenzimidazole main chain simultaneously stabilizes phosphoric acid and preserves continuous proton transport pathways. Strong ion‐pair and hydrogen‐bond interactions suppress acid leaching while maintaining high conductivity, enabling stable and durable high‐temperature fuel cell ...
Huina Lin, Brian C. Benicewicz
wiley   +1 more source

Concerted Proton and Electron Transfer in Heterogeneous Electrocatalytic CO2 Reduction

Angewandte Chemie, EarlyView.
Concerted proton‐electron transfer (CPET) enables CO2‐to‐CO conversion with significantly reduced energy cost compared to cation‐stabilized pathways. Under controlled mass transport of proton donors, CPET dominates at modest potentials. At higher overpotentials, a cation‐stabilized pathway is found to dominate.
Seonmyeong Noh, Gong Zhang, Megan Kelly, Marcel Schreier   +3 more
wiley   +2 more sources

Topology‐Aware Machine Learning for High‐Throughput Screening of MOFs in C8 Aromatic Separation

Advanced Intelligent Discovery, EarlyView.
We screened 15,335 Computation‐Ready, Experimental Metal–Organic Frameworks (CoRE‐MOFs) using a topology‐aware machine learning (ML) model that integrates structural, chemical, pore‐size, and topological descriptors. Top‐performing MOFs exhibit aromatic‐enriched cavities and open metal sites that enable π–π and C–H···π interactions, serving as ...
Yu Li, Honglin Li, Jialu Li, Wan‐Lu Li
wiley   +1 more source

Monitoring Redox Pathways and Performance Limitations in Lithium‐Sulfur Batteries Using In Situ 7/6Li and 33S NMR Spectroscopies

Angewandte Chemie, EarlyView.
Lithium‐sulfur (Li‐S) batteries contain various NMR‐active nuclear isotopes, including 7Li, 6Li and 33S, which are sensitive to the different chemical reactions that occur during battery cycling. Herein, we use a combination of lithium and sulfur operando NMR spectroscopy to provide new insights at the molecular level, fundamental understanding being ...
Jana B. Fritzke, Sunita Dey, Christopher A. O’ Keefe, Jeongjae Lee, Kazuhiro Kamiguchi, Daisuke Mori, Yuri Nakayama, Clare P. Grey   +7 more
wiley   +2 more sources

Advancements in Graphdiyne‐Based Multiscale Catalysts for Green Hydrogen Energy Conversion

Advanced Intelligent Discovery, EarlyView.
This review systematically explores the fundamental characteristics of graphdiyne (GDY), cutting‐edge field of GDY‐based multiscale catalysts within sustainable energy conversion systems.Special emphasis is placed on the structure‒property relationships in different reactions.
Qian Xiao, Lu Qi, Siao Chen, Yurui Xue
wiley   +1 more source

Chemical Metabolomics: Chemical Biology Tools for Advanced Metabolism Investigations

Angewandte Chemie, EarlyView.
The human metabolism has been investigated for several millennia. The metabolome is known for a high complexity due to a large number of different metabolites that are present at different concentrations. Metabolomics has been developed as a field to investigate the entire human metabolome and to elucidate disease development mechanisms.
Alejandro Torregrosa‐Chinillach, Ioanna Tsiara, Wawrzyniec Haberek, Weifeng Lin, Daniel Globisch   +4 more
wiley   +2 more sources