A Novel Heterometallic Ring {Cr5Ni3} and New {Cr6Co2} and {Cr6Zn2} Rings
A novel heterometallic ring containing five Cr(III) and three Ni(II) centers is reported. It forms an octagon and has a single isomer, as revealed by a combination of magnetic and EPR studies and collision‐induced dissociation mass spectrometry. ABSTRACT A new heterometallic ring, [Me4N][(Me4N)2Cr5Ni3F8(BTFB)16] (BTFB = 3,5‐bis(trifluoromethyl)benzoate)
Abdulelah Alsuhaymi +9 more
wiley +1 more source
Light Stable Isotope Ratios of US Pureed Baby Foods. [PDF]
Verostick KA +4 more
europepmc +1 more source
This work introduces the concept of pseudoglucosinolates (psGSLs) and reports the synthesis and evaluation of nitroreductase‐responsive psGSLs. These compounds represent a complementary prodrug strategy to natural glucosinolates (GSLs) for the controlled release of isothiocyanates (ITCs), enabling bio‐responsive protein labeling, as demonstrated in ...
Claire C. Jimidar +13 more
wiley +1 more source
Human cadaver decomposition islands and forensic taphonomy: gravesoil δ<sup>13</sup>C and δ<sup>15</sup>N enrichment patterns in short (30 d) and extended (900 d) postmortem intervals. [PDF]
Miles KL, Gibbon V, Hayden B.
europepmc +1 more source
Alkali‐Metal Base Catalyzed Electrocyclization of Isoprene Derivatives
Simple and abundant alkali‐metal base catalysis in combination with Lewis basic polyamines enables the electrocyclization of isoprene‐derived trienes to cycloheptadienes under neat conditions. Mechanistic insight supported by DFT guides a scalable route to seven‐membered carbocycles which, after reduction, give saturated cycloalkanes relevant as ...
Mikaël Le Roch +3 more
wiley +1 more source
Sampling consistency matters-Stable isotopes (δ15N and δ13C) exhibit wide variation among individuals within bee species native to North America (Hymenoptera: Apidae). [PDF]
Tsalickis A +3 more
europepmc +1 more source
A Cu2P triangle captured in a tetrapodal phosphane tris(olefin) ligand, where all binding forces are weak apart from the Cu─P interaction. ABSTRACT The molecule Ptrop3 contains in each trop unit (trop = dibenzo[a,d]cyclohepten‐5‐yl) a rigid central seven‐membered ring with an olefinic binding site making Ptrop3 potentially a tetradentate ligand ...
Zhongshu Li +6 more
wiley +1 more source
Recent production rates of cosmogenic nuclides in the igneous rocks of Jezero crater floor, Mars. [PDF]
Zorzano M- +2 more
europepmc +1 more source
Catalyst‐Free Cyanation of Arenes by Acetonitrile in a Plasma–Liquid Microreactor
An original approach of arylnitrile synthesis was developed by generating an argon plasma in contact with solutions of arene in acetonitrile within a gas‐liquid microreactor. Plasma activation of acetonitrile generated cyano radicals, enabling a catalyst‐free C‐H cyanation of arenes.
Pierre Dedieu +4 more
wiley +1 more source
Multi-Country Study of Stable Isotopes and Mineral Elements in European Pork. [PDF]
Pinna A +14 more
europepmc +1 more source

