Results 141 to 150 of about 155,621 (344)

Surface Graphitized Mesoporous Carbon Surpasses the Conductivity–Porosity Trade‐Off

open access: yesAdvanced Science, EarlyView.
Electrochemical cathodic polarization in molten CaCl2‐NaCl converts mesoporous carbon (MC) into surface‐graphitized mesoporous graphite, simultaneously increasing surface area (397–867 m2/g) and electrical conductivity (26–450 S/cm) without mass loss.
Juntian Fan   +12 more
wiley   +1 more source

A Generalized Approach for Distal C–H Arylation of Organic Building Blocks: Unveiling the Role of Counter Anion

open access: yesAdvanced Science, EarlyView.
We report a general strategy for meta‐selective C–H arylation using aryl iodides and a Pd(II)/Pd(IV) catalytic system guided by a removable directing group. DFT and experimental studies reveal that counter anion tuning (acetate to trifluoroacetate) significantly enhances selectivity.
Jagrit Grover   +6 more
wiley   +1 more source

Beyond Sabatier: Multiplicate Spillover Phenomena for Manipulating Catalytic Dynamics in Various Electrocatalysis

open access: yesAdvanced Science, EarlyView.
Various spillover‐mediated electrocatalytic reactions, such as hydrogen and oxygen evolution, carbon dioxide and nitrogen reduction, and methanol oxidization reactions, are systematically summarized. Abstract Spillover phenomenon, which is characterized by the dynamic migration of active species across catalyst surfaces, provides a promising avenue to ...
Di Wang   +5 more
wiley   +1 more source

Weakened Isotope Altitude Gradient in the Central Asian Water Tower: Role of Topography and Local Circulation

open access: yesWater Resources Research
The altitude effect (AE) of stable isotopes in meteoric water (δ18O and δ2H), that is, the depletion of water isotopes with increasing altitude, is an important theoretical assumption of isotope‐based paleoaltimetry. However, this assumption has recently
Yudong Shi   +8 more
doaj   +1 more source

Ab initio calculations of the carbon and oxygen isotopes: Energies, correlations, and superfluid pairing

open access: yesPhysics Letters B
We perform ab initio nuclear lattice calculations of the neutron-rich carbon and oxygen isotopes using high-fidelity chiral interactions. We find good agreement with the observed binding energies and compute correlations associated with each two-nucleon ...
Young-Ho Song   +7 more
doaj   +1 more source

Polyoxometalate as Hydrogen–Electron Hub in Metal–Organic Complex for Electrocatalytic Nitrate Reduction to Ammonia

open access: yesAdvanced Science, EarlyView.
To tackle low electrocatalytic nitrate reduction to ammonia efficiency in neutral media, this work designs chain‐like dinuclear/trinuclear polyoxometalate‐based metal‐organic complexes. Metal clusters provide nitrate adsorption/activation sites, while polyoxometalates (POMs) drive water dissociation to generate active hydrogen (*H) that migrates to ...
Qiushuang Jiang   +5 more
wiley   +1 more source

(Appendix A2) Stable oxygen isotope ratios of Globigerina bulloides from sediment core SO161/5_50SL in the Peru-Chile Trench

open access: green, 2008
Susanne Blumberg   +6 more
openalex   +1 more source

Computation‐Guided Dual‐Site Electrocatalysts for Record‐Performance Nitrite‐to‐Ammonia Conversion

open access: yesAdvanced Science, EarlyView.
Designing Cu doped ZnO catalysts for NO2RR via first principles calculation and boosting electrocatalytic nitrite reduction through Cu‐ZnO synergistic deoxygenation, hydrogenation, and NH3 desorption. Cu doping elevates the d‐band center of Zn, strengthening *NO2 binding and deoxygenation, while ZnO sites regulate water adsorption and dissociation ...
Hui Zhang   +15 more
wiley   +1 more source

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