Iron Catalyzed Aryl–Aryl Kumada Cross‐Coupling: A Mechanistic and Computational Investigation
Despite intense interest, the mechanism of iron‐catalyzed aryl–aryl cross‐coupling remains poorly understood. Combining Mössbauer spectroscopy, kinetics analysis, and DFT computations these studies reveal a novel Fe(I)/Fe(II)/Fe(III) catalytic for aryl–aryl cross‐coupling mediated by an Fe(II) PCNHCP Pincer complex. These findings close a key knowledge
Jatin Panda +11 more
wiley +2 more sources
Does Risk Formulation Help Independent Review Board Decisions on Release of Prisoners? A Qualitative Study With Parole Board Members in England and Wales. [PDF]
McMurran M, Payne L, Harrop A, Bowes N.
europepmc +1 more source
Objective Sporadic late‐onset Alzheimer's disease (AD) is characterized by a long pre‐clinical phase where amyloid‐beta (Aβ) and tau begin to accumulate in the brain. The primary objective was to determine the age at which AD starts by finding the average population age when both positron emission tomography (PET) Aβ (Aβ‐PET) and plasma Aβ42/40 become ...
Rodrigo Cánovas +29 more
wiley +1 more source
Psychiatric Risk Governance Across Jurisdictions: A Comparative Analysis of Involuntary Treatment, Community Treatment Orders, and Forensic Mental Health Services. [PDF]
Lippi M +15 more
europepmc +1 more source
Objective The optimal treatment for distal medium vessel occlusion (DMVO) stroke remains uncertain, and evidence comparing endovascular therapy (EVT) with medical management (MM) is limited. We aimed to develop and validate a predictive modeling tool to assess individual treatment benefit in DMVO stroke using explainable counterfactual treatment ...
Mohamed F. Doheim +14 more
wiley +1 more source
Multi blockchain architecture for judicial case management using smart contracts. [PDF]
Alyas T +7 more
europepmc +1 more source
The Racial Antecedents to Federal Sentencing Guidelines: How Congress Judged the Judges from Brown to Booker [PDF]
Murakawa, Naomi
core +1 more source
Public Perceptions of Judges' Use of AI Tools in Courtroom Decision-Making: An Examination of Legitimacy, Fairness, Trust, and Procedural Justice. [PDF]
Fine A, Berthelot ER, Marsh S.
europepmc +1 more source

