Results 91 to 100 of about 12,886 (205)

Tailoring High‐Valent Iron‐Oxo Species Redox via Extended π‐Fe3d–O2p Orbital Overlapping Toward Chemical‐Efficient Water Purification

Angewandte Chemie, EarlyView.
We address the long‐standing challenge of reactivity–selectivity trade‐off by precisely tuning the redox properties of Fe(IV), rather than simply accelerating its formation, to enable chemically efficient and low‐emission water treatment. ABSTRACT High‐valent iron oxo species (Fe(IV)) are attractive for wastewater treatment because of their high ...
Hongyu Zhou, Junwen Chen, Jiuyi Wang, Xinhao Wang, Qiming Zhang, Shiying Ren, Xuning Li, Li Gao, Shaobin Wang, Xiaoguang Duan   +9 more
wiley   +2 more sources

Limited Agreement Between Perceptual and Physiological Heat Strain at Initial Stay Times for Continuous Work in the Heat Before Heat Alleviation Controls

American Journal of Industrial Medicine, EarlyView.
ABSTRACT Introduction Accurate assessment of heat strain at initial stay time (IST; core temperature 38.0°C or Δ1.0°C above resting), when heat mitigation decisions are required, is critical for managing occupational heat exposure. We evaluated the relationship and agreement between physiological (Physiological Strain Index [PSI] and adaptive PSI [aPSI]
Gil Bourgois, Kristina‐Marie T. Janetos, Fergus K. O'Connor, Leonidas G. Ioannou, Glen P. Kenny   +4 more
wiley   +1 more source

Glutathione‐Responsive Acyl‐Modifications for Targeted RNA Decaging and Prolonged Protein Synthesis

Angewandte Chemie, EarlyView.
The self‐immolation of disulfide‐based mRNA modifications in response to endogenous glutathione (GSH) promotes a gradual release of translatable mRNA within the cell, leading to improved nuclease resistance, tunable release properties, and a significant increase (up to 600%) of target protein production over time. This strategy offers an exciting proof
Mary E. Flood, Sathishkumar Kurusamy, Mark Berney, C. Mark Smales, Elizabeth M. Topp, Joanna F. McGouran, Steven Ferguson   +6 more
wiley   +2 more sources

Anadolu’da Türk Kent Kültürünü Oluşturan Mekânsal Yapılanmalar (XI. Yüzyıldan XIII. Yüzyılın Sonuna Kadar)

Ahbar
XI. yüzyıldan itibaren Türkistan ve İran’dan Anadolu’ya göç etmeye başlayan Türkler, aynı yüzyılın ikinci yarısında bu coğrafyayı kendilerine yurt edinmeye başlamışlardır.
Yavuz Selim Altınok
doaj   +1 more source

Timing of Work‐Rest Implementation Influences Worker Productivity Under Heat Stress: Evidence for Initial Stay Time‐Based Scheduling

American Journal of Industrial Medicine, EarlyView.
ABSTRACT Introduction Work‐rest allocations recommended by the American Conference of Governmental Industrial Hygienists (ACGIH) limit heat strain and are typically implemented from the onset of work. Whether delaying implementation until after the initial stay time (IST; the duration of continuous work before core temperature reaches 38.0°C) improves ...
Glen P. Kenny, Kelli E. McCormick, Katie E. Wagar, Roberto C. Harris‐Mostert, James J. McCormick, Leonidas G. Ioannou, Fergus K. O'Connor   +6 more
wiley   +1 more source

Mekanın diyalojisi: Kent mekanı-Kent öznesi

, 2013
Space has been discussed from sociology to architecture, from philosophy to cinema and a variety of academic disciplines and areas; each from different perspectives and forms in the context of their own conceptual framework. For a long time, dealt within the limits of Euclidean geometry and Cartesian philosophy, space has been considered as an absolute
openaire   +2 more sources

Rerouting Oxygen Evolution Through Interfacial Carbonate Chemistry in Near‐Neutral Seawater Electrolysis

Angewandte Chemie, EarlyView.
Carbonate species play a previously overlooked role in near‐neutral seawater electrocatalysis. By coupling electrochemical hydrodynamics with mesoscopic simulations, we reveal a plausible carbonate‐mediated route in which carbonate functions as an interfacial proton acceptor and water as the oxygen donor, showing a possible mechanistic picture of ...
Miao Wang, Masaki Takeguchi, Ken Sakaushi   +2 more
wiley   +2 more sources

On the Prospects for African Philosophy in Australia

Australian Journal of Social Issues, EarlyView.
ABSTRACT This paper grapples with the situation of people of African descent in Australia by working through the constitution of the body of academic philosophy in the country. It contends with the parochialism of the Australian philosophical community and the prospects for the cultivation of greater pluralism. Taking African philosophy as one possible
Bryan Mukandi
wiley   +1 more source

Unraveling A4GALT Mechanism and Its Modulation With Adamantyl‐Galactosylceramide Analogues: Advancing Fabry Disease Therapeutic Strategies

Angewandte Chemie, EarlyView.
A 310‐helix‐mediated conformational switch promotes a front‐face SNi‐like catalysis by human A4GALT. Mechanism‐guided design identifies AdaGalCer as a selective modulator of globotriaosylceramide (Gb3) biosynthesis, opening a clear route toward new Fabry disease therapeutics.
Nicky de Koster, Òscar Vidal‐Gironès, Rowan de Graaf, Ken Kok, Lindsey T. Lelieveld, Jackelien Hoogervorst, Maria J. Ferraz, José Pablo Rivas‐Fernández, Rob F. Lammers, Herman S. Overkleeft, Johannes M. F. G. Aerts, Rolf G. Boot, Carme Rovira, Marta Artola   +13 more
wiley   +2 more sources

Seats and the City: Sitting as an Idle Act in Ankara Neighbourhoods

PLANARCH - Design and Planning Research
This paper re-evaluates the relationship between walking and idleness in evolving urban contexts, proposing that sitting can be understood as a new form of idleness in response to the accelerating speed of urban routines. Drawing on the established urban
Sezin Sarıca, Bengisu Derebaşı
doaj   +1 more source