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Kerogen based characterization of major gas shales: Effects of kerogen fractionation
Organic Geochemistry, 2015Abstract Research into the origin and the mode of entrapment and expulsion of natural gas from unconventional plays requires the isolation and separation of kerogen in its purest and most intact form from the rock matrix. This study expands on the comparative analysis of the effects that isolation methods, conservative closed system versus ...
Denet Pernia +2 more
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Diagenetic modification of kerogens
Philosophical Transactions of the Royal Society of London. Series A, Mathematical and Physical Sciences, 1985Abstract Kerogen is the part of sedimentary organic matter that is not petroleum. It can be isolated by using acid destruction of minerals, except in recent sediments where this procedure results in important hydrolysis reactions. Whether the scale of observation is microscopic or molecular, kerogens are heterogeneous mixtures whose ...
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A reappraisal of kerogen formation
Geochimica et Cosmochimica Acta, 1989Abstract Comparative microscopical and chemical studies of recognizable entities in kerogen and their extant counterparts suggest a new and simple mechanism of kerogen formation which clarifies the interrelationships between extant biomass, kerogen, and fossil fuels.
E.W Tegelaar +3 more
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On the mechanism of kerogen pyrolysis
Fuel, 1984Abstract Aromaticities determined by 13 C n.m.r. are reported for five shale oil samples (Green River formation) prepared under widely different pyrolysis conditions. In the absence of high-pressure hydrogen, the total amount of aromatic carbon in the products is nearly twice that in the raw shale.
Alan K. Burnham, James A. Happe
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1978
As sedimentation and subsidence continue, temperature and pressure increase. In this changing physical environment, the structure of the immature kerogen is no longer in equilibrium with its surroundings. Rearrangements will progressively take place to reach a higher, and thus more stable, degree of ordering.
Bernard P. Tissot, Dietrich H. Welte
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As sedimentation and subsidence continue, temperature and pressure increase. In this changing physical environment, the structure of the immature kerogen is no longer in equilibrium with its surroundings. Rearrangements will progressively take place to reach a higher, and thus more stable, degree of ordering.
Bernard P. Tissot, Dietrich H. Welte
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Kerogen: Composition and Classification
1978The term kerogen will be used here to designate the organic constituent of the sedimentary rocks that is neither soluble in aqueous alkaline solvents nor in the common organic solvents. This is the most frequent acceptance of the term kerogen, and results from a direct generalization to other rock types of the definition by Breger (1961) in ...
Bernard P. Tissot, Dietrich H. Welte
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Sticky layers affect oil transport through the nanopores of realistic shale kerogen
Fuel, 2022Sen Wang +2 more
exaly

