Results 101 to 110 of about 107,082 (295)

Remote Modulation of Single‐Atom Catalyst Boosts High‐Valent Cobalt–Oxo Species Generation for Water Purification and Detoxification

Advanced Science, EarlyView.
This study develops a phosphorus‐doped cobalt single‐atom catalyst that enhances high‐valent cobalt–oxo species generation for water purification. This atomic‐level tuning boosts the catalyst's activity by 3.5 times, enabling efficient pollutant degradation. A continuous‐flow reactor achieves high, long‐term removal efficiency, producing water with low
Wen‐Min Wang, Zheng‐Wei Yang, De‐Xiu Wu, Wen‐Long Wang, Qian‐Yuan Wu   +4 more
wiley   +1 more source

primary kinetic isotope effect

, 2014
Citation: 'primary kinetic isotope effect' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.P04833 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms ...
openaire   +1 more source

A Perspective on the Applications of Triphasic Gas Storage in Electrochemical Systems

Advanced Science, EarlyView.
Gas storage in microporous materials positioned locally at an electrode or electrocatalyst surface enhances electrochemical processes. Abstract Microporous materials store gases under dry conditions (e.g., hydrogen or oxygen via physisorption), but in some cases microporous materials also show triphasic (e.g., in a solid|gas|liquid system) gas storage ...
Zhongkai Li, Corin T. Scott, Taku Suzuki‐Osborne, John P. Lowe, Dominic Taylor, Mariolino Carta, Neil B. McKeown, Andrew D. Burrows, Lucia H. Mascaro, Frank Marken   +9 more
wiley   +1 more source

ISOLUTION 1.0: an ISOtope evoLUTION model describing the stable oxygen (δ18O) and carbon (δ13C) isotope values of speleothems

International Journal of Speleology, 2019
Stable oxygen and carbon isotope ratios (δ13C and δ18O) are the most applied climate and environmental proxies in speleothems allowing to infer past changes in cave drip water δ13C and δ18O related to climate and environmental variations from above the ...
Michael Deininger, Denis Scholz
doaj   +1 more source

normal kinetic isotope effect

, 2014
Citation: 'normal kinetic isotope effect' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.N04213 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms ...
openaire   +1 more source

Nanoconfinement‐Steered Molecular Preorganization Enables Efficient Monoethanolamine Degradation through Electronically Modulated High‐Valent Iron–Oxo Pathways

Advanced Science, EarlyView.
Precise modulation of reaction pathways remains an unresolved challenge in peroxymonosulfate‐activated advanced oxidation processes. The spatial preorganization strategy in engineered confinement architecture enables regioselective bond cleavage in monoethanolamine via synergistic proton–electron transfer, redirecting its degradation from nonselective ...
Lin Zhang, Qin Dai, Xinyue Chen, Hang Yuan, Lei Xing, Zhimo Fang, Xiuze Li, Xiangke Wang, Lihui Zhang, Junping Zhao, Qiangwei Li, Lidong Wang   +11 more
wiley   +1 more source

Der Übergangszustand der bimolekularen Eliminierung (E2-Reaktion) aufgrund neuerer kinetischer Isotopeneffektstudien

CHIMIA, 1977
A discussion of the concerted E2 mechanism is presented with special emphasis on the model of the variable transition state. Sufficient evidence for the concertedness is based on primary β-hydrogen and α-heavy atom kinetic isotope effects.
Alfred V. Willi
doaj   +1 more source

Measurement of the isotopic composition of hydrogen and helium nuclei in cosmic rays with the PAMELA experiment

, 2013
The satellite-borne experiment PAMELA has been used to make new measurements of cosmic ray H and He isotopes. The isotopic composition was measured between 100 and 600 MeV/n for hydrogen and between 100 and 900 MeV/n for helium isotopes over the 23rd ...
Adriani, O., Barbarino, G. C., Bazilevskaya, G. A., Bellotti, R., Boezio, M., Bogomolov, E. A., Bongi, M., Bonvicini, V., Borisov, S., Bottai, S., Bruno, A., Cafagna, F., Campana, D., Carbone, R., Carlson, P., Casolino, M., Castellini, G., Danilchenko, I. A., De Pascale, M. P., De Santis, C., De Simone, N., Di Felice, V., Formato, V., Galper, A. M., Karelin, A. V., Koldashov, S. V., Koldobskiy, S., Krutkov, S. Y., Kvashnin, A. N., Leonov, A., Malakhov, V., Marcelli, L., Mayorov, A. G., Menn, W., Mikhailov, V. V., Mocchiutti, E., Monaco, A., Mori, N., Nikonov, N., Osteria, G., Palma, F., Papini, P., Pearce, M., Picozza, P., Pizzolotto, C., Ricci, M., Ricciarini, S. B., Rossetto, L., Sarkar, R., Simon, M., Sparvoli, R., Spillantini, P., Stozhkov, Y. I., Vacchi, A., Vannuccini, E., Vasilyev, G., Voronov, S. A., Wu, J., Yurkin, Y. T., Zampa, G., Zampa, N., Zverev, V. G.   +61 more
core   +1 more source

Recent Advances in Mediator and Proton Relay Usage in Molecular Catalysis

Advanced Science, EarlyView.
The use of electron–proton transfer mediators, redox mediators, and proton relays in synergy with molecular catalysts in energy‐related small‐molecule and organic transformations is discussed, with a focus on recent advances. Linear free‐energy relationship and catalytic Tafel plots provide a systematic foundation for benchmarking these catalytic ...
Yu‐Lin Chi, Wei‐Shuo Chuang, Jing‐Ke Lin, Yu‐Heng Wang   +3 more
wiley   +1 more source

secondary kinetic isotope effect

, 2014
Citation: 'secondary kinetic isotope effect' in the IUPAC Compendium of Chemical Terminology, 3rd ed.; International Union of Pure and Applied Chemistry; 2006. Online version 3.0.1, 2019. 10.1351/goldbook.S05525 • License: The IUPAC Gold Book is licensed under Creative Commons Attribution-ShareAlike CC BY-SA 4.0 International for individual terms ...
openaire   +1 more source