Frontispiece: Inverse Kinetic Solvent Isotope Effect in TiO2 Photocatalytic Dehalogenation of Non‐adsorbable Aromatic Halides: A Proton‐Induced Pathway [PDF]
Wei Chang+9 more
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Pyrazine‐Functionalized Ru(II)‐Complexes as Visible‐Light Activated Photobases
Visible light excitation leads to the accumulation of electron density in pyrazine‐containing Ru(II) complexes via metal‐to‐ligand charge transfer (MLCT). In aqueous solutions of appropriate pH, excited‐state proton transfer (ESPT) takes place on a timescale of hundreds of ps.
Niklas Klosterhalfen+6 more
wiley +1 more source
Elucidation of Mechanism of Action in Drug Invention: Using Stable Isotope Tracers to Unravel Biochemical Kinetics. [PDF]
Kohnz RA+10 more
europepmc +1 more source
Kinetic isotope effect in direct ethane dissociation on Pt(111)
Mark C. McMaster, R. J. Madix
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Photocatalytic Hydrophosphination Using Calcium Precatalysts
Calcium compounds are competent photocatalysts for hydrophosphination. Returning to the compounds reported by Barrett and Hill, visible light irradiation at ambient temperature activates simple calcium derivatives comparable to thermal catalysis. Ancillary ligands are key to radical versus nonradical reactivity under these conditions.
Moniruzzaman Moniruzzaman+2 more
wiley +1 more source
Carbon kinetic isotope effect in the reaction CH4+Cl: a relative rate study using FTIR spectroscopy
John N. Crowley+4 more
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Kinetics of hydride-transfer reactions from hydrosilanes to carbenium ions. Substituent effects in silicenium ions [PDF]
Basso, Nils+2 more
core +1 more source
Conformational Switch in the Alpha‐Synuclein C‐Terminal Domain Directs Its Fibril Polymorphs
The conformational state of the C‐terminal domain determines the fibril morphology of full‐length wild‐type alpha‐synuclein: high C‐terminus flexibility promotes twisted fibrils, while partial C‐terminal folding drives the assembly of rod‐like fibrils.
Cesar Aguirre+25 more
wiley +1 more source
Observation of the solvent enantio-isotope effect in asymmetric ring-opening of cyclic diaryliodoniums with selenocyanate. [PDF]
Li Y, Tao C, Duan L, Gu Z.
europepmc +1 more source