An Experimental Benchmark for the Barrier Height of an On-Surface Reaction: Hydrogen Oxidation on Pt(332). [PDF]
Nitz F +5 more
europepmc +1 more source
Ring Formation in Sesquiterpene Synthesis: Biomimetic vs. Non‐Biomimetic Strategies
A short review of cyclase enzyme‐mediated ring formation in sesquiterpene biosynthesis is presented as a prelude to six case studies examining the merits and demerits of biomimetic vs. non‐biomimetic strategies for carbocyclisation in the total synthesis of this iconic natural product class.
Bohan Lin, Chen Dai, Alan C. Spivey
wiley +1 more source
A universal O-glycosylation platform enabled by pyridinium catalysis using gas-releasing oxazolidinone-based carbamates donors. [PDF]
Qin X +9 more
europepmc +1 more source
This work presents ZIF‐derived ultrafine CdxZn1−xS decorated with Pt sub‐nanoclusters for efficient photocatalytic reforming of lactic acid. The catalyst achieves high H2 evolution (270.6 mmol h−1 g−1) and selective pyruvic acid production (73.1%), with mechanistic insights revealing Pt‐mediated control over reaction pathways.
Feng Liu +5 more
wiley +1 more source
Solvent-Dependent Change in the Rate-Determining Step of Au(I)-Catalyzed <i>N</i>-Propargyl Benzamide Cyclization. [PDF]
Norman SG +5 more
europepmc +1 more source
Plasma Activate Nitrogen for Efficient Ammonia Synthesis
This review systematically summarizes the classification and reaction mechanism of plasma, and discusses the synergy between different plasmas and catalytic methods along with energy consumptions in detail, in order to gain a deeper understanding of currently ammonia synthesis strategies.
Yamei Zhang +8 more
wiley +1 more source
HNO Dimerization as a Chemical Reference Standard for N<sub>2</sub>O Isotopomer Ratio: Ab Initio Calculations, Formation Kinetics, and Frequency Comb Spectroscopy. [PDF]
Sadiek I +3 more
europepmc +1 more source
Hydrogen/Deuterium Exchange for Chiral Stability Assessment in Acidic Methine-Containing Compounds. [PDF]
Yu ZJ +11 more
europepmc +1 more source
Kinetic Resolution of Heterocyclic Lactams by a Photocatalytic Cobalt-Catalyzed Dehydrogenation. [PDF]
Zhou C, Bach T.
europepmc +1 more source
Visible Light Promoted Alkenyl C-H Bond Addition to Dienes and Aldehydes for the Synthesis of Frameworks Relevant to Polyketide Natural Products. [PDF]
Ohno S +4 more
europepmc +1 more source

