Results 61 to 70 of about 340 (151)
Janus Reactivity of a Mononuclear Non‐Heme Iron(III)‐Peroxo Complex Toward Indole Oxidation
Angewandte Chemie, EarlyView.The iron(III)‐peroxo complex [FeIII(O2)(12‐TMC)]+ exhibits bifurcating pathways in indole oxidation. N─H indoles undergo N─H H‐atom abstraction, supported by a KIE of 5.2 for N─H/N–D 2,3‐dimethylindoles, whereas N‐methylindoles react via electrophilic addition of the iron‐peroxo group to the C2–C3 double bond of the indole ring, forming iron ...
Wenjuan Zhu +4 more
wiley +2 more sources
Metagenomic Sequencing of Lloviu Virus from Dead Schreiber's Bats in Bosnia and Herzegovina. [PDF]
Microorganisms, 2023 Goletic S +10 more
europepmc +1 more source
Advanced Science, EarlyView.Stable water‐soluble luminescent tris(2,4,6‐trichlorophenyl)methyl (TTM) radicals, TTM‐trisTP3B and TTM‐trisTP9B, were designed and successfully synthesized. They exhibited deep‐red emissions and high photostability in water. TTM‐trisTP3B exhibited dual functionality as a fluorescence imaging (FI) probe and a magnetic resonance imaging (MRI) contrast ...
Kosuke Anraku +6 more
wiley +1 more source
Noncanonical Peloruside A Biosynthesis by an Uncultivated Verrucomicrobiota Symbiont
Angewandte Chemie, EarlyView.Noncanonical biochemistry of the peloruside PKS characterized in this work, comprising double bond generation by a noncanonical tridomain (blue), acetyl‐CoA recycling (orange), and proofreading systems (purple and yellow). The Z‐double bond is installed by TEB1 through O‐acetylation and acetate elimination. The acyl ligase PelB (AL, orange) selectively
Amy E. Fraley +11 more
wiley +2 more sources
Advanced Science, EarlyView.Pathological tissue rigidity mechanoprimes microglia by enhancing actin cytoskeleton–nucleus coupling and chromatin opening at rigidity‐responsive cis‐regulatory elements (mechanoCREs). Subsequent NF‐κB/p65 signaling converges on this permissive regulatory state to amplify inflammatory gene expression and microglial activation.
Yu Xuan Meng +15 more
wiley +1 more source
Orchestrating Anion–π+ Interactions to Accelerate Metal‐Free Room‐Temperature Phosphorescence
Angewandte Chemie, EarlyView.Tuning anion–π+ interactions in pyridinium iodide contact ion pairs enables ultrafast metal‐free room‐temperature phosphorescence (540–605 nm) with radiative rates up to 5.2×105 s−1. Strong iodide→π+ charge‐transfer coupling, enhanced spin–orbit interactions, and dynamic ion‐pair organization accelerate intersystem crossing and emission, establishing ...
Eetu Hakkarainen +12 more
wiley +2 more sources
Advanced Science, EarlyView.Void morphology at the lithium metal‐solid electrolyte contact governs electrochemical contact stability in all‐solid‐state batteries. This work resolves the competing roles of electrochemical reaction, bulk vacancy diffusion, and distinct surface diffusion pathways in dictating the size and morphology evolution of a single void and its transition to a
Sourim Banerjee +3 more
wiley +1 more source
Transforming a Library Service within a Provincial Healthcare Organization: Forging a New Path
Journal of the Canadian Health Libraries Association, 2018 Introduction: Prior to 2011, libraries within Alberta Health Services (AHS) operated using a variety of self-determining service models across 19 locations.
Morgan Lorraine Truax +2 more
doaj +1 more source
Geological Substrate Effects on Teucrium montanum L. (Lamiaceae) Morphological Traits: Geometric Morphometrics Approach. [PDF]
Plants (Basel), 2023 Zlatić N, Budečević S, Stanković M.
europepmc +1 more source
Advanced Science, EarlyView.A synergistic phosphor‐sensitization strategy (PSS) significantly enhances ternary OSCs performance. By integrating an Ir‐3 complex as a triplet energy mediator within a pyrazine‐based (N2) ternary blend (PM6:N2: L8‐BO) doped with 1 wt.% of Ir‐3 complex, and a PCE of 18.6% is achieved through efficient triplet‐triplet energy transfer (TTET), suppressed
Priyanka Yadav +11 more
wiley +1 more source