Results 111 to 120 of about 7,483 (251)

β‐Ketonitrile‐Modified Prodan Derivatives as Large‐Stokes‐Shift Solvatochromic Fluorophores With Enhanced Brightness and Ratiometric Thermometric Response

open access: yesChemistry – A European Journal, EarlyView.
We report a systematic study of β‐ketonitrile–modified Prodan‐type solvatochromic fluorophores. The β‐ketonitrile substitution induces marked bathochromic shifts in absorption and emission and significantly enhances fluorescence quantum yields in nonpolar solvents.
Hiroaki Asakawa   +3 more
wiley   +1 more source

Tailoring Liquid Crystalline Self‐Assembly and Photophysical Properties of Unsymmetrical Fluorenones via Polar Terminal Groups

open access: yesChemistry – A European Journal, EarlyView.
Novel liquid crystalline fluorenones bearing various head groups were synthesized and characterized. By alteration of the head group, N, SmC, or SmA phases were obtained, and emission properties could be tuned depending on solvent or temperature. ABSTRACT In this work, a series of novel unsymmetrical fluorenone derivatives bearing various head groups ...
Falk Feucht   +5 more
wiley   +1 more source

Europium Doped Atomically Precise Bismuth Oxido Nanoclusters as Molecular Building Blocks for Photoluminescent Hybrid Materials

open access: yesChemistry – A European Journal, EarlyView.
Europium doping of bismuth oxido nanoclusters (BiO‐NCs) provides stable hosts for Eu3+ in an asymmetric coordination environment, which in turn results in an intense 5D0→7F0 transition and long luminescence lifetimes. Transparent hybrid materials showing characteristic red photoluminescence are accessible via radical copolymerisation of these soluble ...
Rico Thomas   +5 more
wiley   +1 more source

Rapid Exploration of Mixture Adsorption via Adiabatic Sampling. [PDF]

open access: yesJ Phys Chem C Nanomater Interfaces
Desgranges C, Delhommelle J.
europepmc   +1 more source

Proximal Steric Shielding Unlocks High Solid‐State Luminescence in Quinoxaline‐Fused Pyrene Heteroacenes

open access: yesChemistry – A European Journal, EarlyView.
Proximal steric tuning of quinoxaline‐fused pyrene heteroacenes enables soluble derivatives that exhibit solid‐state photoluminescence quantum yields (PLQYs) up to 82%, surpassing previous benchmarks. This work reveals key structure–property relationships for next‐generation, processable organic emitters in advanced optoelectronic applications ...
Rafiq Ahamed   +9 more
wiley   +1 more source

Chiral Dipicolinamide‐Based Push–Pull π‐Conjugated Systems as Nonreciprocal Circularly Polarized Luminescence Emitters

open access: yesChemistry – A European Journal, EarlyView.
This work presents the synthesis and characterization of chiral dipicolinamide push–pull fluorophores. While possessing similar photophysical properties in solution, their solvent‐annealed thin films exhibit unexpected, nonreciprocal chiroptical activity in both absorption and emission, including a complete inversion of the chiroptical profile upon ...
Filippo Petri   +3 more
wiley   +1 more source

Tracking the Complex Dynamics of Electron-Transfer-Mediated Decay in Real Space and Time. [PDF]

open access: yesJ Am Chem Soc
Trinter F   +17 more
europepmc   +1 more source

Crystallization‐Induced Emission Enhancements of Hybrid Butenolide‐Diphenylethenes

open access: yesChemistry – A European Journal, EarlyView.
Hybrid butenolide‐diphenylethene fluorophores show crystallization‐induced emission enhancement (CIEE), with substituents tuning solid‐state quantum yields up to 50%. One derivative, BuCM, displays dual‐state emissions (DSE), making this compact scaffold a promising platform for CIEE/DSE‐active fluorophores.
Sujlesh Sharma   +3 more
wiley   +1 more source

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