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The chemistry of krypton

Coordination Chemistry Reviews, 2002
Abstract Krypton is the only noble gas other than xenon to give rise to isolable compounds in macroscopic amounts, although the chemistry of krypton is presently limited to the +2 oxidation state. The strong oxidant-fluorinator properties and thermal instabilities of krypton(II) compounds have posed considerable challenges to determining the extent ...
Gary J Schrobilgen
exaly   +3 more sources

Krypton-krypton molecular interaction

Physica, 1961
Abstract Mainly on the basis of the various crystal properties the potential energy of interaction of krypton on a six-parameter model has been obtained. The potential energy curve thus obtained is more logical than those on the usual two or three parameter models (e.g. exp-6, L-J (6–12) etc.). It has been found that the force constants on the L-J
A. K. Barua, P.K. Chakraborti
openaire   +2 more sources

Properties of metastable krypton atoms in afterglows produced in krypton and krypton–nitrogen mixtures

The Journal of Chemical Physics, 1976
Light absorption techniques are used to study the temporal dependence of the number densities of the 5s′00 and 5s12 krypton metastable atoms during the decay period (afterglow) of a pulsed discharge in krypton and krypton–nitrogen mixtures. The sensitivity of the temporal properties of the 5s′00 state of krypton to discharge pulse conditions was ...
C. J. Tracy, H. J. Oskam
openaire   +2 more sources

The Compressibility of Krypton. I. An Equation of State for Krypton and the Weight of a Liter of Krypton

The Journal of Chemical Physics, 1952
The compressibility of krypton containing 0.90 mole percent xenon has been measured from 0° to 300°C and over the density range 1 to 10 mole per liter. The constants of the Beattie-Bridgeman equation of state for the sample and for pure krypton were determined. The constants for pure krypton are R=0.08206, A0=2.4230, a=0.02865, B0=0.05261, b=0, c=14.89×
James S. Brierley   +2 more
openaire   +2 more sources

On the excitation of krypton

Journal of Applied Spectroscopy, 1965
The populations of the 1s, 2p, and 3p levels of krypton have been determined. The electrical parameters of the glow discharge have been measured by the two-probe method. The oscillator strengths of 13 spectral lines of krypton were determined in the visible and near-infrared portions of the spectrum.
E. P. Ostapchenko, V. P. Malakhov
openaire   +2 more sources

Analysis of Krypton-85 and Krypton-81 in a Few Liters of Air

Analytical Chemistry, 2014
Long-lived radioactive krypton isotopes, (81)Kr (t1/2 = 229,000 year) and (85)Kr (t1/2 = 10.76 year), are ideal tracers. (81)Kr is cosmogenic and can be used for dating groundwater beyond the (14)C age. (85)Kr is a fission product and can be applied in atmospheric studies, nuclear safety inspections, and dating young groundwater.
Gu-Liang Liu   +5 more
openaire   +3 more sources

MAD phasing with krypton

Acta Crystallographica Section D Biological Crystallography, 2001
Experiments demonstrating the feasibility of Kr-edge MAD on frozen crystals as a routine method for structure determination are reported. Approximately 50% of protein crystals can be successfully derivatized by pressurization with the noble gases xenon or krypton. While Xe has produced many useful derivatives for MIR phasing over the last several years,
Nicole Kresge   +3 more
openaire   +3 more sources

Viscosity and Thermal Conductivity of Binary Gas Mixtures: Krypton-Argon, Krypton-Neon, and Krypton-Helium [PDF]

open access: possibleProceedings of the Physical Society, 1961
The coefficients of viscosity and thermal conductivity of binary mixtures of krypton with argon, neon and helium have been determined over the full range of composition of each mixture at a pressure of 70 cm of mercury and at a temperature in the range 18.0 to 18.3°C.
openaire   +1 more source

Surface diffusion of metastable krypton atoms on krypton-doped solid argon

Journal of Luminescence, 1998
Abstract Besides desorption and surface trapping of selectively excited Kr atoms at the surface of Kr-doped Ar crystals, a new relaxation mechanism has been observed. It includes surface diffusion of long-living atomic-type surface centers and guest-molecule formation at the surface.
Runne, M., Zimmerer, G.
openaire   +3 more sources

Enhancement in Mercury–Krypton and Xenon–Krypton Gaseous Discharges

Applied Optics, 1963
Spectroscopic examination of electrodeless gaseous discharges in krypton containing small amounts of xenon or mercury shows a directed transfer of energy by collisions of the second kind from the krypton 1s5 metastable atoms to the 2s levels in Xe and the 91P1 state in Hg.
G. Grosof, R. Targ
openaire   +2 more sources

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