Expanding the Scope of Indium in Frustrated Lewis Pair Chemistry
Chemistry – A European Journal, EarlyView.All good things come in threes: The pyridine‐“protected” FLP tBu2InCH2PtBu2·Py shows three different kinds of reactivity: Besides “typical” FLP activity, it prefers formation of the “soft” isomers for substrates with multiple sites for FLP attack, but reacts with SO2 as a “masked” In/C FLP by insertion into the In─C bond.
Daniel N. Heuer +5 more
wiley +1 more source
Nonlinear Responses and Decoupling Between Soil Organic Carbon Fractions and Extracellular Enzyme Activity Across Salt-Affected Soils of the Qiangtang Plateau. [PDF]
Biology (Basel)Chen C +7 more
europepmc +1 more source
Chiral Pyrazolinylidene Complexes for Asymmetric Catalysis
Chemistry – A European Journal, EarlyView.The synthesis and application of pyrazolin‐5‐ylidene NHC chiral‐at‐ruthenium catalysts is reported. The strong donating pyrazolin‐5‐ylidene ligands led to highly electron rich ruthenium complexes, which showed excellent catalytic activity and enantioselectivity in the intramolecular aziridination of an alkene.
Felix Möller +6 more
wiley +1 more source
Rice Cultivation Duration Drives Soil Organic Carbon Stabilization in Saline-Alkaline Paddy Soils via Mineral-Associated Organic Carbon Accumulation and Biological Pathways. [PDF]
Biology (Basel)Xu F +10 more
europepmc +1 more source
Chemistry – A European Journal, EarlyView.Several new chiral cyclic hypervalent iodine(III) reagents have been synthesized and characterized. Carbon‐based ligands were successfully installed onto the hypervalent iodine centers, giving thus access to novel chiral cyano‐, trifluoromethyl‐ or alkynyl‐bearing λ3‐iodanes.
Emmanuel Valzer +4 more
wiley +1 more source
Afforestation does not increase the temperature sensitivity of soil organic carbon decomposition in the water-level fluctuation zone. [PDF]
Front Plant SciLei Y +11 more
europepmc +1 more source
Lability of dissolved organic carbon in Arctic rivers on the North Slope of Alaska
, 2007 Rivers are an important pathway of organic carbon-mobilization in the arctic, and their influence is projected to grow as precipitation and soil temperatures increase in response to highlatitude warming. This study addresses the bioactivity of arctic riverine dissolved organic carbon (DOC) in three North Slope Alaskan rivers: the Kuparuk, the Colville,
openaire +1 more source
Chemistry – A European Journal, EarlyView.Seven novel supramolecular photosensitizers based on benzo[c][1,2,5]thiadiazole (BTZ) tethered to calix[4]arene (C[4]) scaffolds are reported with facile, scalable, and selective syntheses. Their abilities to produce singlet oxygen have been tested through the photo‐oxidation of α‐terpinene.
Leonardo Amicosante +6 more
wiley +1 more source
The Response of Heterotrophic Prokaryote and Viral Communities to Labile Organic Carbon Inputs Is Controlled by the Predator Food Chain Structure. [PDF]
Viruses, 2017 Sandaa RA +7 more
europepmc +1 more source
A Stable Isopterin Mimic of a Potent Bacterial Stimulant of T Cells
Chemistry – A European Journal, EarlyView.A microbial metabolite covalently binds immunological protein MR1 to potently activate specific lymphocytes called MAIT cells, but it is too unstable for biological applications. Here, using synthesis, assays, protein crystallography, and computer modelling, we report a water‐stable analogue that activates reporter cells expressing the MAIT T cell ...
Jeffrey Y. W. Mak +9 more
wiley +1 more source