Results 171 to 180 of about 87,265 (295)

One‐Pot Transition‐Metal‐Free Methods for the Synthesis of All Three Bonds of the Alkyne's Triple Bond

open access: yesChemistry – A European Journal, EarlyView.
One‐pot transition‐metal‐free methods for the synthesis of all three bonds of the alkyne's triple bond are reviewed. After analysis of several named reactions and discussion of improvements, recent advances in the synthesis of alkynes are discussed. Each section contains a proposed reaction mechanism and analysis of the strengths and weaknesses of the ...
Eugene Kim   +4 more
wiley   +1 more source

Distinct Ligand‐ and Metal‐Centered Phosphorescence in a Terbium Carbazolyl Complex

open access: yesChemistry – A European Journal, EarlyView.
Terbium and lanthanum carbazolide complexes show two distinct modes of luminescence: Strongly temperature‐dependent narrow‐line terbium emission could be induced. In addition, both the terbium and the lanthanum complexes show broad‐line interligand emission processes with excited states of microsecond life‐time.
Xiaofei Sun   +9 more
wiley   +1 more source

Fluorescence Properties and Mg2+ Selectivity of Aryl‐Alkynyl Derivatives of the o‐Aminophenoltriacetate (APTRA) Ligand

open access: yesChemistry – A European Journal, EarlyView.
It is a challenge to improve the selectivity of high‐denticity ligands for Mg2+ over Ca2+. We show that in aryl‐alkynyl derivatives of APTRA, electron‐withdrawing substituents lower the binding affinity for Ca2+ more than Mg2+, making the ligand more selective for Mg2+.
Laura L. Duncan   +2 more
wiley   +1 more source

Silent Partners in the Mill: Unveiling the Role of Additives in Mechanochemical Synthesis

open access: yesChemistry – A European Journal, EarlyView.
Mechanochemistry offers a sustainable, solvent‐free alternative to traditional synthesis, often enhanced by additives in a process known as additive‐assisted grinding. This review discusses how various additives, including liquids, ionic solids, and advanced materials like ionic liquids and piezoelectric compounds, improve reaction efficiency ...
Johanna Breinsperger   +3 more
wiley   +1 more source

Photocatalytic Degradation of PFOA with Porous Lanthanoid Perovskites Nano Catalyst

open access: yesChemie Ingenieur Technik, EarlyView.
Photocatalytic degradation of PFOA was studied using nickel‐ and lanthanide‐doped perovskites under UV–VIS irradiation. Catalyst characterization confirmed successful doping, with Ni/NdMnO3 showing the highest photocatalytic efficiency. Degradation occurred via C–C bond cleavage, forming transformation products PFHpA and PFHxA.
Julia Schowarte   +5 more
wiley   +1 more source

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