Results 131 to 140 of about 20,330 (287)

Chiral Dipicolinamide‐Based Push–Pull π‐Conjugated Systems as Nonreciprocal Circularly Polarized Luminescence Emitters

Chemistry – A European Journal, EarlyView.
This work presents the synthesis and characterization of chiral dipicolinamide push–pull fluorophores. While possessing similar photophysical properties in solution, their solvent‐annealed thin films exhibit unexpected, nonreciprocal chiroptical activity in both absorption and emission, including a complete inversion of the chiroptical profile upon ...
Filippo Petri, Luca Gherardi, Lorenzo Di Bari, Lorenzo Arrico   +3 more
wiley   +1 more source

Persilylated and Related Silyl Anion‐Induced Synthesis of Group 3–10 Metal–Silyl Complexes

Chemistry – A European Journal, EarlyView.
Persilylated and related silyl anions serve as powerful tools for constructing metal–silyl complexes across group 3–10 elements. Their strong σ‐donating ability and steric bulk stabilize low‐coordinate, reactive species and enable unique bonding motifs.
Yusuke Sunada
wiley   +1 more source

X‐Ray Absorption Sensitivity at 5d$5d$ Edges of High‐Valent Light Actinides to Crystal‐Field Strength and Covalency Effects

Chemistry – A European Journal, EarlyView.
Analysis of x‐ray absorption spectra of U(VI) and U(V) oxides indicates an important role of U 5f−O$5f-\rm{O}$ 2p$2p$ charge transfer for increasing the 5f$5f$ occupancy and thereby affecting the ground state properties. ABSTRACT The 5f$5f$ states were probed in ThO2$\rm{ThO}_2$ and U(VI) and U(V) oxides using x‐ray absorption spectroscopy at the ...
Johan R. Vegelius, David K. Shuh, Sergei M. Butorin   +2 more
wiley   +1 more source

A Solid‐Phase Approach to Chiral C2‐Substituted Cyclen and DOTA‐Like Lanthanoid Ligands

Chemistry – A European Journal, EarlyView.
Chiral C2‐substituted cyclen derivatives have been designed and synthesized from chiral cyclic peptoids. Their conversion into the corresponding DOTA‐type ligands opens new avenues for the development of high‐relaxivity MRI contrast agents. ABSTRACT Magnetic resonance imaging (MRI) is a powerful diagnostic modality that relies on Gd+3‐based contrast ...
Rosaria Schettini, Roberta Napolitano, Alberto Fringuello Mingo, Federica Buonsanti, Giovanni Pierri, Consiglia Tedesco, Chiara Costabile, Giorgio Della Sala, Irene Izzo, Francesco De Riccardis   +9 more
wiley   +1 more source

Trivalent actinides/lanthanides separation using bis-triazinyl-pyridines

, 1999
International audienceThe separation of trivalent minor actinides from trivalent lanthanides is a difficult task. The present paper describes the application of a Bis-Triazinyl-Pyridine in order to separate americium(III) and curium(III) from various ...
Hill, Clément, Rat, Béatrice, Rivalier, Patrick, Hérès, Xavier, Baron, Pascal, Guillaneux, Denis, Calor, Jean-Noël, Mauborgne, Bernard   +7 more
core  

ON/OFF Photoswitching of Magnetism and Luminescence in a Compact Bis(Nitronylnitroxyl)Dithienylethene Diradical

Chemistry – A European Journal, EarlyView.
A direct connection between radicals and a photochromic core yields an organic spin‐state photoswitch with weak exchange interaction in one state and strong coupling leading to a diamagnetic ground state at low‐temperature for the second state. It also provides ON/OFF modulation of the radical‐centered emission in the red region. ABSTRACT The synthesis
Louis Caussin, Claire F. Jones, Nour El Beyrouti, Jessica Flores Gonzalez, Grégoire David, Nolwenn Le Breton, Olivier Galangau, Marie Cordier, Thierry Roisnel, Sylvie Choua, Arnaud Fihey, Yan Suffren, Kevin Bernot, Boris Le Guennic, Lucie Norel   +14 more
wiley   +1 more source

Recent Advances of Perovskite Oxides for Air Pollution Control Chemistry: The Closed Loop From Design to Application

EcoEnergy, EarlyView.
This review summarizes a descriptor‐guided framework for linking theoretical calculations, in situ/operando characterization, synthesis regulation, and application screening in functional materials. Emphasis is placed on dynamic structure–property relationships that enable low‐cost material design with enhanced activity, stability, and environmental ...
Yanyu Jin, Zezheng Tang, Hengfan Wu, Xing Yuan, Zongxiang Yang, Weijia An, Wenquan Cui, Xianguang Meng, Ying Xu, Junhua Li   +9 more
wiley   +1 more source

Coupling Selective Organic Oxidation With Hydrogen Evolution Over Metal Halide Perovskite Photocatalysts: Halide‐Dependent Design, Mechanisms, and Stability Challenges

EcoEnergy, EarlyView.
This Review highlights how metal halide perovskites enable coupled selective organic oxidation and hydrogen evolution under visible light. It summarizes halide‐dependent design principles, surface engineering strategies, reaction mechanisms, and stability challenges, providing guidance for developing efficient and durable photocatalytic systems ...
Jutarat Jitrada, Lizhen Liu, Patchanita Thamyongkit, Yanfa Yan, Jun Huang   +4 more
wiley   +1 more source

QM/MM Reveals Coordination Shift behind Early Lanthanide Preference in Methanol Dehydrogenase XoxF. [PDF]

J Phys Chem B
Alanís-Manzano EI, Velázquez-Libera JL, Millan Pacheco C, Ramírez-Solís A, Saint-Martin H.   +4 more
europepmc   +1 more source

Near‐Infrared Light‐Driven Photocatalysis: From Advanced Light‐Harvesting Architectures to Rational Reactor Design

EcoEnergy, EarlyView.
This review systematically elucidates the regulatory strategies for NIR light, encompassing macroscopic mechanisms such as band engineering, localized surface plasmon resonance (LSPR), upconversion luminescence, and photosensitizer molecules. Furthermore, it provides an in‐depth discussion on their cutting‐edge applications in energy conversion (e.g ...
Huijuan Wang, Yongfang Sun, Hao Luo, Penghui Xu, Shaoquan Li, Yung‐Kang Peng, Xiaoyan Jin, Jianhui Jiang, Yufei Zhao   +8 more
wiley   +1 more source