Results 201 to 210 of about 16,640 (300)

Alkaline‐Earth Metal Complexes Based on Tridentate β‐Diketiminate Ligands Bearing a Tethered Secondary Amine: Synthesis and Characterization

open access: yesZeitschrift für anorganische und allgemeine Chemie, EarlyView.
Deprotonotion of a β‐diketiminate ligand with a tethered secondary amine resulted in highly stable heteroleptic complexes, but the formation of the dianionic ligand could not be achieved. The alkaline‐earth (Ae) metal chemistry of a β‐diketiminate (BDI) ligand with a bulky Ar‐substituent and a pendant amine arm was investigated. The ligand precursor HC[
Bastian Rösch   +6 more
wiley   +1 more source

Synthesis and Characterization of Anhydrous Cerium(III) Acetate, [Ce(CH3COO)3], and its Interconversions to Hydrated Phases

open access: yesZeitschrift für anorganische und allgemeine Chemie, EarlyView.
The crystal structure of anhydrous cerium(III) acetate [Ce(CH3COO)3] is reported. Additionally, the interconversions in the cerium(III) acetate hydrate system were studied by in situ and ex situ PXRD. We report the synthesis and crystal structure of anhydrous cerium(III) acetate [Ce(CH3COO)3] (1) as well as the interconversions to different hydrated ...
Niklas Ruser   +7 more
wiley   +1 more source

Absorption Spectra of the Lanthanides in Fused Salt Media

open access: yes
This report addresses the absorption spectra of the Lanthanides in fused salt ...
Heusinkveld, Merlyn R.   +1 more
core  

Organotitanyl “TiCp” Fragment Capping the Bowl‐Shaped Unit in the Ternary Anion [(Cp)Ti(Sn3Bi3)]2−

open access: yesZeitschrift für anorganische und allgemeine Chemie, EarlyView.
A novel ternary anion, [(η5‐Cp)Ti(Sn3Bi3‐κ3)]2− composed of a cyclopentadienyl titanium fragment coordinated by a Sn3Bi3 bowl‐shaped cluster unit, is reproted. Unlike homoatomic nine‐atom clusters of heavier tetrel elements, which retain their identity upon dissolution, intermetalloid clusters are not formed directly from ternary alkali‐metal alloys in
C. E. Fajman   +3 more
wiley   +1 more source

Expanding the Reactivity of Masked Divalent Lanthanide-Isocarbonyl Complexes. [PDF]

open access: yesOrganometallics
Temple SR   +4 more
europepmc   +1 more source

Synchrotron beamline setup enabling quasi‐simultaneous PXRD and XANES measurements: case study of Fischer–Tropsch catalyst reduction at 60 bar

open access: yesJournal of Synchrotron Radiation, EarlyView.
This paper presents a beamline setup that allows the combination of in situ powder X‐ray diffraction (PXRD) and X‐ray absorption near‐edge structure (XANES) measurements within a single experimental cycle to investigate cobalt catalyst structures and properties under real conditions.Powder X‐ray diffraction (PXRD) and X‐ray absorption near‐edge ...
Lipeng Yao   +4 more
wiley   +1 more source

Gepta‐EX: a multi‐channel germanium detector for X‐ray absorption fine structure

open access: yesJournal of Synchrotron Radiation, EarlyView.
Gepta‐EX is a compact seven‐channel high‐purity germanium detector designed to deliver high‐resolution fluorescence X‐ray absorption fine‐structure measurements at photon energies where silicon detectors become effectively transparent. It provides excellent energy resolution across a broad energy range, avoids silicon escape‐peak artifacts, and offers ...
Abdul K. Rumaiz   +6 more
wiley   +1 more source

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