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Lanthanide Diatomics and Lanthanide Contractions
The Journal of Physical Chemistry, 1995Density functional (DF) calculations including gradient-exchange and correlation corrections have been performed on the LnH, LnO, and LnF series (Ln = La, Gd, Yb, and Lu). Relativistic first-order perturbations including S-O couplings are accounted for. The calculated molecular constants are in reasonable agreement with the experimental ones.
S. G. Wang, W. H. E. Schwarz
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Accounts of Chemical Research, 2018
The use of earth-abundant, cheap, potent, and readily available lanthanide photocatalysts provides an opportunity to complement or even replace rare and precious metal photosensitizers. Moreover, lanthanide photosensitizers have been demonstrated for the generation of a variety of reactive species, including aryl radicals, alkyl radicals, and others ...
Yusen Qiao, Eric J. Schelter
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The use of earth-abundant, cheap, potent, and readily available lanthanide photocatalysts provides an opportunity to complement or even replace rare and precious metal photosensitizers. Moreover, lanthanide photosensitizers have been demonstrated for the generation of a variety of reactive species, including aryl radicals, alkyl radicals, and others ...
Yusen Qiao, Eric J. Schelter
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Synthesis of lanthanide and lanthanide-silicate aerogels
Journal of Sol-Gel Science and Technology, 1994In this paper we report on the preparation of mixed lanthanide-silicate and pure lanthanide aerogels from the chlorides of erbium, praseodymium, and neodymium. A two-step sol-gel method is described for preparing the mixed aerogels, using a sub-stoichiometric amount of water in the first step to prepare a partially condensed silica-lanthanide precursor.
T. M. Tillotson +3 more
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Selective crystallization strategies for lanthanide–lanthanide and lanthanide–actinide separations
Chemical Communications.This feature article highlights recent advances in crystallization-based strategies for lanthanide–lanthanide and lanthanide–actinide separations,relevant to rare–earth purification and nuclear fuel reprocessing.
Jiarui Chen, Huangjie Lu, Jian Lin
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Lanthanide corroles: a new class of macrocyclic lanthanide complexes
Chemical Communications, 2013The first examples of lanthanide corroles are prepared by two synthetic routes. (Mes2(p-OMePh)corrole)La·4.5DME (1·4.5DME) and (Mes2(p-OMePh)corrole)Tb·4DME (2·4DME) are prepared from the free base corrole and Ln((NSiMe3)2)3, while (Mes2(p-OMePh)corrole)Gd·TACNMe3 (3·TACNMe3) is prepared by metathesis of the recently reported Li3 corrole and GdCl3.
Heather L, Buckley +3 more
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Design of Lanthanide Fingers: Compact Lanthanide‐Binding Metalloproteins
ChemBioChem, 2010AbstractLanthanides have interesting chemical properties; these include luminescent, magnetic, and catalytic functions. Toward the development of proteins incorporating novel functions, we have designed a new lanthanide‐binding motif, lanthanide fingers.
Christopher W, am Ende +4 more
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From lanthanide chlorides to lanthanide pentafluorophenolates via lanthanide N,N-dialkylcarbamates
Polyhedron, 2015Neodymium and terbium pentafluorophenolates, containing 1,10-phenanthroline as ancillary ligand, [Ln(OC6F5)3(phen)3], (1 Ln = Nd, 2 Ln = Tb) have been synthesized by reacting the N,N-dibutylcarbamato complexes, [Ln(O2CNBu2)3], easily obtained from aqueous solutions of lanthanide salts, with C6F5OH in the presence of 1,10-phenanthroline.
Armelao, Lidia +7 more
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Lanthanides, formerly known as rare earths, are critical materials. Their discovery, extraction and refining are described. The important role China has in refining is outlined, as is its dominant role in production of components such as extremely powerful permanent magnets based on neodymium–iron–boron alloys.
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