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Selective crystallization strategies for lanthanide–lanthanide and lanthanide–actinide separations
Chemical Communications.This feature article highlights recent advances in crystallization-based strategies for lanthanide–lanthanide and lanthanide–actinide separations,relevant to rare–earth purification and nuclear fuel reprocessing.
Jiarui Chen, Huangjie Lu, Jian Lin
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Lanthanide corroles: a new class of macrocyclic lanthanide complexes
Chemical Communications, 2013The first examples of lanthanide corroles are prepared by two synthetic routes. (Mes2(p-OMePh)corrole)La·4.5DME (1·4.5DME) and (Mes2(p-OMePh)corrole)Tb·4DME (2·4DME) are prepared from the free base corrole and Ln((NSiMe3)2)3, while (Mes2(p-OMePh)corrole)Gd·TACNMe3 (3·TACNMe3) is prepared by metathesis of the recently reported Li3 corrole and GdCl3.
Heather L, Buckley +3 more
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Design of Lanthanide Fingers: Compact Lanthanide‐Binding Metalloproteins
ChemBioChem, 2010AbstractLanthanides have interesting chemical properties; these include luminescent, magnetic, and catalytic functions. Toward the development of proteins incorporating novel functions, we have designed a new lanthanide‐binding motif, lanthanide fingers.
Christopher W, am Ende +4 more
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From lanthanide chlorides to lanthanide pentafluorophenolates via lanthanide N,N-dialkylcarbamates
Polyhedron, 2015Neodymium and terbium pentafluorophenolates, containing 1,10-phenanthroline as ancillary ligand, [Ln(OC6F5)3(phen)3], (1 Ln = Nd, 2 Ln = Tb) have been synthesized by reacting the N,N-dibutylcarbamato complexes, [Ln(O2CNBu2)3], easily obtained from aqueous solutions of lanthanide salts, with C6F5OH in the presence of 1,10-phenanthroline.
Armelao L +7 more
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Lanthanide Texaphyrins as Photocatalysts
Inorganic Chemistry, 2018Here, we report the use of gadolinium(III)-, lutetium(III)-, and lanthanum(III)-texaphyrins as bioinspired photocatalysts that promote a novel approach to the degradation of curcumin, a 1,3-diketo-containing natural product. Complexation of curcumin to the lanthanide centers of the texaphyrins yields stable species that display limited reactivity in ...
Aaron D. Lammer +5 more
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Lanthanides, formerly known as rare earths, are critical materials. Their discovery, extraction and refining are described. The important role China has in refining is outlined, as is its dominant role in production of components such as extremely powerful permanent magnets based on neodymium–iron–boron alloys.
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Lanthanides as Anticancer Agents
Current Medicinal Chemistry-Anti-Cancer Agents, 2005The application of inorganic chemistry to medicine is a rapidly developing field, and novel therapeutic and diagnostic metals and metal complexes are now having an impact on medical practice. Advances in biocoordination chemistry are crucial for improving the design of compounds to reduce toxic side effects and understand their mechanisms of action.
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