Hydrophilic Sulfonated Bis-1,2,4-Triazine Ligands Are Highly Effective Reagents for Separating Actinides(III) from Lanthanides(III) via Selective Formation of Aqueous Actinide Complexes [PDF]
We report the first examples of hydrophilic 6,6’-bis(1,2,4-triazin-3-yl)-2,2’-bipyridine (BTBP) and 2,9-bis(1,2,4-triazin-3-yl)-1,10-phenanthroline (BTPhen) ligands, and their applications as actinide(III) selective aqueous complexing agents.
Harwood, Laurence +10 more
core +1 more source
Minor Actinides Can Replace Essential Lanthanides in Bacterial Life** [PDF]
Certain f-block elements—the lanthanides—have biological relevance in the context of methylotrophic bacteria. The respective strains incorporate these 4 f elements into the active site of one of their key metabolic enzymes, a lanthanide-dependent ...
Carolin Rulofs +19 more
core +1 more source
Influence of diluent alkyl substitution on the extraction of Am(III) and Eu(III) by a 6,6’-bis(1,2,4-triazin-3-yl)-2,2’-bipyridine ligand dissolved in alkylated cyclohexanone Diluents [PDF]
Several alkylated cyclohexanones were investigated as potential diluents for the selective extraction of Am(III) from Eu(III) from nitric acid solutions by the CyMe4-BTBP ligand.
Harwood, L.M. +9 more
core +1 more source
Taking Lanthanides out of Isolation: Tuning the Optical Properties of Metal-Organic Frameworks [PDF]
Metal organic frameworks (MOFs) are increasingly used in applications that rely on the optical and electronic properties of these materials. These applications require a fundamental understanding on how the structure of these materials, and in particular
Kyriakos, Stylianou +11 more
core +2 more sources
Persistent luminescence phosphors (PLPs) are largely used in biomedical areas owing to their unique advantages in reducing the autofluorescence and light-scattering interference from tissues.
Xinyuan Qin +3 more
doaj +1 more source
The separation of americium(III) from europium(III) by two new 6,6'-bistriazinyl-2,2'-bipyridines in different diluents [PDF]
The synthesis and extraction of americium(III) and europium(III) from aqueous nitric acid solutions by the new BTBP ligands 6,6’-bis(5,5,7,7- tetramethyl-5,7-dihydrofuro[3,4-e]-1,2,4-triazin-3-yl)-2,2’-bipyridine (Cy5-O-Me4-BTBP), and 6,6’-bis(5,5,7,7 ...
Petr Distler +12 more
core +1 more source
Lanthanides are widely used in several advanced technologies, and the presence of heavy metal ions as traces reduce their efficiencies. Hence, adsorption of some heavy metals from Lanthanides aqueous solution using previously prepared graphene oxide ...
E. M. Abu Elgoud +3 more
doaj +1 more source
Voltammetry in Determination of Trace Amounts of Lanthanides—A Review
This paper presents an overview of approaches proposed in the scientific literature for the voltammetric determination of rare earth elements (mainly cerium and europium individually, as well as various lanthanides simultaneously) in manifold kinds of ...
Malgorzata Grabarczyk +2 more
doaj +1 more source
Complexation of lanthanides, actinides and transition metal cations with a 6-(1,2,4-triazin-3-yl)-2,2’:6’,2’’-terpyridine ligand: implications for actinide(III) /lanthanide(III) partitioning [PDF]
The quadridentate N-heterocyclic ligand 6-(5,5,8,8-tetramethyl-5,6,7,8-tetrahydro-1,2,4-benzotriazin-3-yl)-2,2’:6’,2’’-terpyridine (CyMe4-hemi-BTBP) has been synthesized and its interactions with Am(III), U(VI), Ln(III) and some transition metal cations ...
Whittaker, Daniel +19 more
core +1 more source
LANTANIDES (Y, La, Ce, Pr, Nd, Sm) AND ACTINIDS (Th, U) IN SOILS OF THE HIBINO-LOVOZERO PROVINCE
In the Khibinsko-Lovozero district of the Kola Peninsula, the territory is divided into three geochemically different areas. In the background area near Umbozero, both mineral and peated samples contain all rare metals below clark: lanthanides and ...
Yu. Vodianitsky +2 more
doaj +1 more source

