Results 51 to 60 of about 36,714 (273)

Recent Advances in the Study of Trivalent Lanthanides and Actinides by Phosphinic and Thiophosphinic Ligands in Condensed Phases

Molecules, 2023
The separation of trivalent actinides and lanthanides is a key step in the sustainable development of nuclear energy, and it is currently mainly realized via liquid–liquid extraction techniques.
Qin Wang, Ziyi Liu, Yu-Fei Song, Dongqi Wang   +3 more
doaj   +1 more source

Ensemble v-representable ab-initio density functional calculation of energy and spin in atoms: atest of exchange-correlation approximations

, 2010
The total energies and the spin states for atoms and their first ions with Z = 1-86 are calculated within the the local spin-density approximation (LSDA) and the generalized-gradient approximation (GGA) to the exchange-correlation (xc) energy in density ...
Eli Kraisler, Guy Makov, Itzhak Kelson, J. Perdew, L. D. Landau, R. G. Parr, R. M. Dreizler, R. Martin, R. van Leeuwen, V. L. Moruzzi   +9 more
core   +1 more source

Lanthanide-induced relaxation anisotropy [PDF]

Physical Chemistry Chemical Physics, 2018
Lanthanide-induced nuclear spin relaxation in liquid state is anisotropic in the molecular frame.
Elizaveta A. Suturina, Kevin Mason, Carlos F. G. C. Geraldes, Nicholas F. Chilton, David Parker, Ilya Kuprov   +5 more
openaire   +5 more sources

Synchrotron Radiation for Quantum Technology

Advanced Functional Materials, EarlyView.
Materials and interfaces underpin quantum technologies, with synchrotron and FEL methods key to understanding and optimizing them. Advances span superconducting and semiconducting qubits, 2D materials, and topological systems, where strain, defects, and interfaces govern performance.
Oliver Rader, Sakura Pascarelli, Klaus Attenkofer, Anna A. Makarova, Karsten Holldack, Kai Rossnagel, Kristiaan Temst, George Kourousias, Stefano Carretta, Caterina Biscari, Helmut Dosch   +10 more
wiley   +1 more source

Atomic Size Misfit for Electrocatalytic Small Molecule Activation

Advanced Functional Materials, EarlyView.
This review explores the application and mechanisms of atomic size misfit in catalysis for small molecule activation, focusing on how structural defects and electronic properties can effectively lower the energy barriers of chemical bonds in molecules like H2O, CO2, and N2.
Ping Hong, Changfan Xu, Huaping Zhao, Yong Lei   +3 more
wiley   +1 more source

Supercharged fluorescent proteins detect lanthanides via direct antennae signaling

Nature Communications
A sustainable operation for harvesting metals in the lanthanide series is needed to meet the rising demand for rare earth elements across diverse global industries.
Kevin Y. Huang, Lizette Cardenas, Andrew D. Ellington, David J. F. Walker   +3 more
doaj   +1 more source

Lanthanide Single-Molecule Magnets [PDF]

Chemical Reviews, 2013
Researchers demonstrate that lanthanide single-molecule magnets (SMM) have the potential for new technological applications. SMMs can be considered as molecular analogues of classical bulk ferromagnets, making it possible to develop them for applications involving the storage and processing of digital information.
Woodruff, Daniel N., Winpenny, Richard E P, Layfield, Richard A.   +2 more
openaire   +3 more sources

Biodegradable and Recyclable Luminescent Mixed‐Matrix‐Membranes, Hydrogels, and Cryogels based on Nanoscale Metal‐Organic Frameworks and Biopolymers

Advanced Functional Materials, EarlyView.
The study presents biodegradable and recyclable mixed‐matrix membranes (MMMs), hydrogels, and cryogels using luminescent nanoscale metal‐organic frameworks (nMOFs) and biopolymers. These bio‐nMOF‐MMMs combine europium‐based nMOFs as probes for the status of the materials with the biopolymers agar and gelatine and present alternatives to conventional ...
Moritz Maxeiner, Julian Burkhart, Kateryna Borysova, Chiara Mazzariol, Klaus Müller‐Buschbaum   +4 more
wiley   +1 more source

Recovery of lanthanides and yttrium from single super phosphate fertilizer using D2EHPA and a synergistic D2EHPA-TBP mixture [PDF]

مجله علوم و فنون هسته‌ای, 2015
The recovery of lanthanides (lanthanum, cerium, erbium, and europium) and yttrium from nitrate leach liquor of single super phosphate fertilizer was investigated using di-(2-ethylhexyl) phosphoric acid (D2EHPA).
Saeid AlamdarMilani, SeyedHossein Nazemi, Bahram Rezaei   +2 more
doaj  

Complexation of lanthanides, actinides and transition metal cations with a 6-(1,2,4-triazin-3-yl)-2,2’:6’,2’’-terpyridine ligand: implications for actinide(III) /lanthanide(III) partitioning [PDF]

, 2012
The quadridentate N-heterocyclic ligand 6-(5,5,8,8-tetramethyl-5,6,7,8-tetrahydro-1,2,4-benzotriazin-3-yl)-2,2’:6’,2’’-terpyridine (CyMe4-hemi-BTBP) has been synthesized and its interactions with Am(III), U(VI), Ln(III) and some transition metal cations ...
Albrecht, Albrecht, Alexander, Amoroso, Amoroso, Amoroso, Andreiadis, Banik, Baum, Benay, Benay, Benay, Berthet, Berthet, Berthet, Berthet, Boucher, Calderazzo, Che, Choppin, Choppin, Clint A. Sharrad, Colette, Colette, Colette, Comblin, Constable, Constable, Constable, Constable, Constable, Constable, Constable, Constable, Constable, Constable, Cordier, Cosier, Dam, Daniel Whittaker, Dell'Amico, Dell'Amico, Dell'Amico, Denecke, Denecke, Deneil, Desreux, Desreux, Dolomanov, Drew, Drew, Drew, Drew, Drew, Ekberg, Ekberg, El Aroussi, Ephritikhine, Fife, Foreman, Frank W. Lewis, Françoise Arnaud-Neu, Galaup, Gampp, Gampp, Gampp, Gampp, Gaunt, Geist, Girnt, Giuseppe Modolo, Hagström, Harwood, Heirtzler, Heirtzler, Hubscher-Bruder, Hudson, Hudson, Ionova, Ito, Iveson, Jones, Keizers, Kikuchi, Kolarik, Laurence M. Harwood, Lewis, Lewis, Lewis, Lewis, Madic, Magill, Magnusson, Marcos, Marcos, Mathur, Michael G. B. Drew, Michael J. Hudson, Michal Sypula, Mincher, Mincher, Mukkala, Nash, Nilsson, Pabst, Pabst, Pabst, Palatinus, Peters, Piguet, Pompidor, Potts, Ranganathan, Retegan, Rice, Salvatores, Sheldrick, Stefankiewicz, Steppert, Steppert, Thummel, Trumm, Trumm, Tsang, Vladimira Videva, Véronique Hubscher-Bruder, Walesa-Chorab, Wang   +127 more
core   +2 more sources