Pushing the Boundary of Covalency in Lanthanoid‐Tellurium Bonds: Insights from the Synthesis, Molecular and Electronic Structures of Low‐Coordinate, Monomeric Europium(II) and Ytterbium(II) Tellurolates [PDF]
, 2023 Owing to the strict hard/soft dichotomy between the lanthanoids and tellurium atoms, and the strong affinity of lanthanoid ions for high coordination numbers, low-coordinate, monomeric lanthanoid tellurolate complexes have remained elusive as compared to
Peter C. Junk +15 more
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Influence of magmatic and volatile evolution upon lanthanoid fractionation within peralkaline magmas (Norra Kärr, Sweden) [PDF]
, 2022 The lanthanoid elements, and in particular the heavier lanthanoids, are essential in the manufacture of advanced technologies due to their unique magnetic, spectral and luminescence properties.
Dobrzański, Andrew Jan
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The true nature of SmSb2O4Cl : syntheses and crystal structures of Sm2[Sb4O8]Cl2 and Eu2[Sb4O8]Cl2 [PDF]
, 2023 The two lanthanoid oxidoantimonate(III) chlorides SmSb2O4Cl and EuSb2O4Cl are accessible from solid‐state reactions of Sb2O3 with Ln2O3 and LnCl3 (Ln=Sm and Eu) at 750 °C for two days. They crystallize in the centrosymmetric tetragonal space group P4/ncc
Locke, Ralf J. C., Schleid, Thomas
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Revised ionic radii of lanthanoid(III) ions in aqueous solution
, 2011 International audienceA new set of ionic radii in aqueous solution has been derived for lanthanoid(III) cations starting from a very accurate experimental determination of the ion–water distances obtained from extended X-ray absorption fine structure ...
Vitorge, Pierre +16 more
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Synthesis, crystal structure and properties of the new laminar quaternary tellurides SrLnCuTe3 (Ln = Sm, Gd-Tm and Lu) [PDF]
, 2023 This paper reports for the first time on the new laminar quaternary orthorhombic heterometallic quaternary tellurides SrLnCuTe3, the fabrication of which has been a challenge until this work.
Garmonov, Alexander A. +6 more
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Lutetium(III) aqua ion : On the dynamical structure of the heaviest lanthanoid hydration complex. [PDF]
, 2016 International audienceThe structure and dynamics of the lutetium(iii) ion in aqueous solution have been investigated by means of a polarizable force field molecular dynamics (MD).
d'Angelo, Paola +5 more
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The size of actinoid(III) ions - structural analysis vs. common misinterpretations [PDF]
, 2016 A fundamental property of ions is their size, a known fact since before the acceptance of the modern atom model. The common way to describe the size of an ion is to determine its radius, defined as one of a pair of radii adding up to the bond distance ...
Lundberg, Daniel, Persson, Ingmar
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Syntheses, structures and reactivity of organolanthanoid complexes [PDF]
, 2017 The focus of this thesis is divided into two directions. The first explores the pseudo- Grignard reaction involving the oxidative addition of aryl halide to lanthanoid metals (Yb, Eu) (Chapter two).
Ali, Safaa Hussein
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, 2019 Ytterbium is the penultimate element of the lanthanoid series. It is thus one of the heavy lanthanoid elements and lies between thulium and lutetium. Its discovery is attributed to the Swiss chemist Jean Charles Galissard de Marignac in 1878.
Deacon, Glen B. +2 more
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Revised Ionic Radii of Lanthanoid(III) Ions in Aqueous Solution
, 2016 A new set of ionic radii in aqueous solution has been derived for lanthanoid(III) cations starting from a very accurate experimental determination of the ion–water distances obtained from extended X-ray absorption fine structure (EXAFS) data. At variance
Sacha Abadie (1284105) +7 more
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