Results 41 to 50 of about 65,509 (236)

Mimicking Block Copolymer Self‐Assembly with One‐Pot Synthesized Polyphosphoester Gradient Copolymers

Advanced Functional Materials, EarlyView.
Degradable Polyphosphoester (PPE) gradient copolymers (GCPs) are synthesized via one‐pot copolymerization. We show that GCPs self‐assemble into nanostructures like polymersomes, effectively mimicking the behavior of traditional BCPs. The gradient strength is key, with softer gradients favoring micelles.
Suna Azhdari, Timo Rheinberger, Ulrich Mansfeld, Yorick Post, Jürgen Linders, Olga Koshkina, André H. Gröschel, Frederik R. Wurm   +7 more
wiley   +1 more source

Organometallic Precursor‐Induced Gradient Architecture on Multilayer Nanoporous Graphene Membranes for Precise Organic Solvent Nanofiltration

Advanced Functional Materials, EarlyView.
Alumina growth narrows surface pores and seals non‐selective defects, enhancing selectivity while preserving the nanoporous graphene architecture. Additionally, the deposition enables gradient‐controlled structural modification, with intergrown alumina acting as a physical cross‐linker that stabilizes the laminar structure.
Junhyeok Kang, Hwayong Lee, Suseong Hyun, Jiwon Kim, Ju Yeon Kim, Jeongyeob Oh, Yunseong Ji, Byungchan Han, Dae Woo Kim   +8 more
wiley   +1 more source

Atomic‐Level Ionic Displacement Polarization Enhanced Piezocatalytic Hydrogen Evolution in Covalent Organic Frameworks

Advanced Functional Materials, EarlyView.
Two isomorphic COFs were synthesized and compared, including an amphoteric COF (SQ‐TAPT) and a neutral COF (PDA‐TAPT). The ionic bonds in SQ‐TAPT introduce more Born effective charges, thereby enhancing its ionic displacement polarization. Experimental and theoretical calculations demonstrated that SQ‐TAPT exhibited higher polarity and stronger ...
Ge Yan, Xiaodong Sun, Kailai Zhang, Shuai Zhang, Haijun Hu, Hui Li, Zhenglong Li, Hongwei Huang, Liqun Ye, Jiyang Li, Yunling Liu, Hongge Pan, Tianyi Ma   +12 more
wiley   +1 more source

Metal–Organic Frameworks for Gaseous Pollutant Management: From Capture to Neutralization and Reutilization

Advanced Functional Materials, EarlyView.
This review maps how MOFs can manage hazardous gases by combining adsorption, neutralization, and reutilization, enabling sustainable air‐pollution control. Covering chemical warfare agent simulants, SO2, NOx, NH3, H2S, and volatile organic compounds, it highlights structure‐guided strategies that boost selectivity, water tolerance, and cycling ...
Yuanmeng Tian, Zeyu Tao, Kaikai Ma, Xiaoliang Wang, Bo Yu, Yiu Wan Yip, Zhijie Chen, Jin Shang, Bin Fei   +8 more
wiley   +1 more source

Unravelling the Atomic Structure of a Metal‐Covalent Organic Framework Assembled from Ruthenium Metalloligands

Advanced Materials, Volume 37, Issue 13, April 2, 2025.
Metal‐covalent organic frameworks (MCOFs) are novel porous materials that exhibit the advantages of covalent and metal‐organic frameworks. However, it is extremely difficult to resolve their atomic structure and better understand their structure‐properties relation. This work utilizes a synergistic combination of advanced microscopy, spectroscopic, and
Seán Hennessey, Roberto González‐Gómez, Nicolás Arisnabarreta, Anna Ciotti, Jing Hou, Nadezda V. Tarakina, Andrey Bezrukov, Kunal S. Mali, Michael Zaworotko, Steven De Feyter, Max García‐Melchor, Pau Farràs   +11 more
wiley   +1 more source

Polarization‐Sensitive Au‐TiO2 Nanopillars for Tailored Plasmonic Enhanced Light‐Driven Reaction Activity

Advanced Optical Materials, EarlyView.
Manipulating the product generation yield is achieved on a model plasmonic resonance‐driven reaction by tuning the nonthermal effects of localized surface plasmonic resonance on an elliptical Au‐TiO2 nanopillar metasurface. Asymmetric configuration of the elliptical nanopillar array governs the polarization‐dependent optical properties redshifting the ...
Ning Lyu, Anjalie Edirisooriya, Zelio Fusco, Dawei Liu, Lan Fu, Fiona J. Beck, Christin David   +6 more
wiley   +1 more source

Regulation of Excitonic Behavior in Defective Acetylenic Polymers Enables Mechanism Switching in O2 Activation for Enhanced Water Decontamination

Advanced Science, EarlyView.
A molecular defect‐mediated charge accumulation strategy is developed to regulate the exciton behavior for selective molecular oxygen (O2)activation in poly(1,3,5‐triethynylbenzene) (PTEB). Artificial internal electric field (IEF) constructed in defective PTEB provides internal driving force to steer the directed migration of charge carriers, thereby ...
Xiaofeng Tang, Sijia Jin, Wei Li, Yingrong Wang, Haiyan Zhang, Zhiqiao He, Shuang Song, Yaqi Cai, Tao Zeng   +8 more
wiley   +1 more source

Thermodynamically Reinforced Dual‐Interface 1D/3D Tin‐Lead Perovskite Heterostructure for Stable All‐Perovskite Tandem Solar Cells

Advanced Science, EarlyView.
A π‐conjugated diammonium additive is employed to engineer a dual‐interface 1D/3D perovskite heterostructure. π‐π stacking 1D perovskitoids act as nucleation templates to relieve tensile strain and intra‐/intergranular disorder and then encapsulate the 3D bulk to fortify the Sn‐I octahedral framework. The all‐perovskite tandem devices based 1D/3D Sn‐Pb
Hui Li, Zhen Liu, Bohong Chang, Yutong Wu, Ruiyang Yin   +4 more
wiley   +1 more source

NEW [SnR2(C2O4)2]2- (R = Ph, Bu) MOIETY CONTAINING ADDUCTS AND COMPLEXES: SYNTHESIS, INFRARED AND MOSSBAUER STUDIES

Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry, 2015
New oxalato and hydrogenoxalato organotin (IV) derivatives containing mono- and bichelating oxalates or a monochelating hydrogenoxalate, have been synthesized and characterized by elemental analyses, infrared and Mossbauer spectroscopy.
YAYA SOW, LIBASSE DIOP
doaj  

Mortise‐Tenon Joint Inspired Weakly Solvated Gel Electrolyte Based on Halogen Bonds for High‐Voltage Lithium Metal Batteries

Advanced Science, EarlyView.
Inspired by “mortise‐tenon joints”, a halogen bond‐mediated solvation regulation strategy is proposed for gel polymer electrolytes. This approach utilizes π‐hole framework directed halogen bond interactions to weaken solvent‐Li+ coordination, thereby inducing an anion‐dominated weakly solvating structure that facilitates the formation of a highly ion ...
Shuohan Liu, Wensheng Tian, Hui Pan, Shunwei Chen, Xiujun Han, Hengdao Quan, Shenmin Zhu   +6 more
wiley   +1 more source