Results 81 to 90 of about 1,046,898 (187)

3D Nano‐architected Polymer Shell Enables Reconfigurable Stabilized Blue Phase Soft Crystals

open access: yesAdvanced Functional Materials, EarlyView.
Spherical polymer shells featuring nanostructure of blue phase (BP) disclinations form via in situ photo‐polymerization within BP liquid crystals, providing controlled anchoring for BP nucleation and growth at room temperature and beyond. This architected confinement enhances BP thermal stability over a broad temperature range while enabling dynamic ...
Sepideh Norouzi   +8 more
wiley   +1 more source

Interfacial Interaction‐Mediated Regulation of Metal Oxidation States for Enhanced CO2 Reduction

open access: yesAdvanced Functional Materials, EarlyView.
A hybrid strategy is employed to optimize bismuth–oxygen interactions, precisely regulating interfacial bismuth–oxygen bonds during topochemical synthesis. This leads to vanadium oxynitride‐bismuth catalyst exhibiting high Faradaic efficiency and durability for formate production, attributed to enhanced reaction thermodynamics and kinetics.
Zhongyuan Ma   +6 more
wiley   +1 more source

f‐p‐d Gradient Orbital Coupling Induced Spin State Enhancement of Atomic Fe Sites for Efficient and Stable Oxygen Reduction Reaction

open access: yesAdvanced Functional Materials, EarlyView.
The f‐p‐d (Eu─O─Fe) gradient orbital coupling induces electron delocalization and the introduced f‐band of Eu shifts the spin state of the Fe center in FePc from low‐spin to intermediate‐spin. This strategy simultaneously enhances oxygen reduction reaction (ORR) activity, reaction kinetics, and stability, resulting in superior ORR performance and ...
Ruiqi Cheng   +7 more
wiley   +1 more source

Self‐Poled Halide Perovskite Ruddlesden‐Popper Ferroelectric‐Photovoltaic Semiconductor Thin Films and Their Energy Harvesting Properties

open access: yesAdvanced Functional Materials, EarlyView.
Low‐dimensional halide perovskite thin films, (BA)2(MA)n‐1PbnBr3n+1 (n = 1, 2), exhibit both semiconducting and ferroelectric properties, enabling mechanical and light energy harvesting. Using Cr/Cr₂O₃ or PCBM as barrier layers ensures reproducible ferroelectricity.
Raja Sekhar Muddam   +8 more
wiley   +1 more source

Sono‐Piezo‐Photosynthesis of Ethylene and Acetylene from Bioethanol under Ambient Conditions

open access: yesAdvanced Functional Materials, EarlyView.
A novel sono‐piezo‐photocatalytic strategy enables the conversion of bioethanol to ethylene (C2H4) and acetylene (C2H2) under ambient conditions, addressing the limitations of conventional methods that are high‐temperature and energy‐intensive. By using an advanced graphene oxide/sodium bismuth titanate heterostructure catalyst, this work achieved ...
Yue Jiang   +21 more
wiley   +1 more source

Gd‐Induced Oxygen Vacancy Creation Activates Lattice Oxygen Oxidation for Water Electrolysis

open access: yesAdvanced Functional Materials, EarlyView.
DFT calculations shows that Gd incorporation into Fe‐doped NiO raises the O 2p band center, lowers oxygen vacancy formation energy, and thus promotes the LOM mechanism for OER. Gd and Fe co‐doped NiO nanosheets synthesized via spray combustion exhibits a low overpotential of 227 mV and maintains stable AEMWE performance for over 120 h, demonstrating ...
Yong Wang   +18 more
wiley   +1 more source

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