Results 131 to 140 of about 12,658 (260)

Site‐Specific Hydroxide Formation and Corrosion on Mg Nanocrystals

open access: yesAdvanced Science, EarlyView.
Using single‐crystalline Mg nanocrystals, this study uncovers the intrinsic corrosion initiation mechanism. The stability of the protective Mg(OH)2 film depends on its interfacial coherence with the Mg substrate. Corrosion initiates at exposed corners, where film coverage is incomplete.
Yao Liu   +8 more
wiley   +1 more source

Electrochemically Induced Oxide‐to‐Hydroxide Transformation Enables Fast Proton Transport for Enhanced Hydrogen Evolution

open access: yesAdvanced Science, EarlyView.
An electrochemically induced transformation of polar MgO(111) into Mg(OH)2(001) creates a proton‐conductive hydroxide layer during hydrogen evolution. Operando synchrotron XRD and DFT reveal a low‐barrier Grotthuss proton‐hopping mechanism, establishing a feasible strategy for designing oxide‐hydroxide electrocatalysts with enhanced proton transport ...
Jiaying Mo   +12 more
wiley   +1 more source

Tailored Catalytic Microenvironments Enable Efficient Electrochemical Ammonia Production

open access: yesAdvanced Science, EarlyView.
This study shows that Co2+ substitution in inverse spinel FeFeCoO4 constructs an integrated catalytic microenvironment for efficient nitrate‐to‐ammonia reduction. Jahn–Teller distortion activates Fe sites for *H generation, while hard–soft acid–base regulated dual‐metal sites optimize proton‐coupled electron transfer and intermediate adsorption ...
Qi Zhang   +8 more
wiley   +1 more source

Hydrophobicity Modulated Interfacial Water Distribution for Enhanced Kinetics of HER

open access: yesAdvanced Science, EarlyView.
In electrocatalysis, hydrophilic structures improve interfacial water management by forming a continuous, compact water film that facilitates proton/hydrogen transport, thereby lowering the effective adsorption free energy of H*. By contrast, hydrophobic structures enable rapid gas transport and promote the capture and local enrichment of gaseous ...
Yucheng Dong   +5 more
wiley   +1 more source

The Third‐Generation Magnetic Super‐Stable Mineralizer: Complete Removal and Separation of Multiple Heavy Metal Pollutants

open access: yesAdvanced Science, EarlyView.
The 3rd‐generation magnetic super‐stable mineralizer M‐MgAl‐700 features a core‐shell structure, strong superparamagnetism, large surface area, and abundant oxygen defects. It achieves exceptional Cd(II) and As(V) mineralization capacities, reducing both pollutants in co‐contaminated water and soil to meet national standards.
Haoran Wang   +9 more
wiley   +1 more source

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