Results 191 to 200 of about 16,803 (245)

Design of an LCST–UCST-Like Thermoresponsive Zwitterionic Copolymer

Langmuir, 2021
Thermoresponsive polymers that possess both UCST- and LCST-like behaviors have generally been designed using diblock copolymers that are mostly composed of an LCST-like polymer and a UCST polymer. Herein, we prepared an LCST-UCST-type polymer composed of UCST-like thermoresponsive zwitterionic sulfabetaine methacrylate and nonthermoresponsive PEG ...
Nobuyuki Morimoto, Masaya Yamamoto
openaire   +2 more sources

Effects of stereochemistry and copolymerization on the LCST of PNIPAm

The Journal of Chemical Physics, 2017
Poly(N-isopropylacrylamide) (PNIPAm) is a smart polymer that presents a lower critical transition temperature (LCST) of 305 K. Interestingly, this transition point falls within the range of the human body temperature, making PNIPAm a highly suitable candidate for bio-medical applications.
Tiago E. de Oliveira   +3 more
openaire   +3 more sources

Thermo‐Responsive Polyoxazolines with Widely Tuneable LCST

Macromolecular Bioscience, 2009
AbstractThe “click” modification of statistical poly[2‐(isopropyl/3‐butenyl)‐2‐oxazoline] copolymers with ω‐functionalized thiols can be used to generate a toolbox of thermo‐responsive polymers. The cloud points of the polymers can be finely tuned over a wide range as a function of composition and hydrophilicity of the side chain (hydrocarbon, alcohol,
Diehl, C., Schlaad, H.
openaire   +3 more sources

Self‐assembled Fluorescent Nanoparticles with Tunable LCST Behavior in Water

Chemistry – An Asian Journal, 2022
AbstractThe development of stimuli‐responsive fluorescent materials in water based on organic molecule has drawn significant interest. Herein, we designed and synthesized an amphiphilic molecule M containing a fixed tetraphenylethylene moiety (FTPE) as hydrophobic part and tri(ethylene glycol) (TEG) chains as hydrophilic part.
Tangxin Xiao   +6 more
openaire   +2 more sources

Triple Hydrophilic UCST–LCST Block Copolymers

Macromolecules, 2016
Thermosensitive ABC triblock copolymers with different block lengths and block orders were prepared by reversible addition–fragmentation chain transfer (RAFT) polymerization. Using a nonionic macro-RAFT agent containing poly(ethylene oxide) (PEO, average degree of polymerization 17), either N-acryloylglycinamide (NAGA) or N-isopropylacrylamide (NIPAM ...
Lauri Mäkinen   +3 more
openaire   +1 more source

A Novel Functional Polymer with Tunable LCST

Macromolecules, 2008
Poly(N-[(2,2-dimethyl-1,3-dioxolane)methyl]acrylamide) (PDMDOMA), a novel thermo-responsive polymer containing pendant dioxolane groups was synthesized via atom transfer radical polymerization (ATRP). Water soluble PDMDOMAs with controlled molecular weight and narrow molecular weight distribution were obtained.
Yuquan Zou   +2 more
openaire   +1 more source

LCST and UCST behavior in polymer solutions and blends

Polymer, 2012
Abstract We introduce a model for polymer solutions and blends that display both an upper and a lower critical solution temperature (UCST, LCST). Using our simple analytic lattice theory along with a fixed parameter set independent of both composition and temperature, we study solutions and blends exhibiting complicated miscibility patterns ...
E.A. Clark, J.E.G. Lipson
exaly   +2 more sources

Molecular Description of the LCST Behavior of an Elastin-Like Polypeptide

Biomacromolecules, 2014
Elastin-like polypeptides (ELPs) with the repeat sequence of VPGVG are widely used as a model system for investigation of lower critical solution temperature (LCST) transition behavior. In this paper, the effect of temperature on the structure, dynamics and association of (VPGVG)18 in aqueous solution is investigated using atomistic molecular dynamics ...
Nan K, Li   +4 more
openaire   +2 more sources

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