Thermodynamic Description of the LCST of Charged Thermoresponsive Copolymers [PDF]
The dependence of the lower critical solution temperature (LCST) of charged, thermosensitive copolymers on their charge fraction and the salt concentration is investigated by employing systematic cloud-point experiments and analytical theory. The latter is based on the concept of the Donnan equilibrium incorporated into a thermodynamic expansion of a ...
Heyda, J. +3 more
openaire +3 more sources
Inducing an LCST in hydrophilic polysaccharides via engineered macromolecular hydrophobicity
AbstractThermoresponsive polysaccharide-based materials with tunable transition temperatures regulating phase-separated microdomains offer substantial opportunities in tissue engineering and biomedical applications. To develop novel synthetic thermoresponsive polysaccharides, we employed versatile chemical routes to attach hydrophobic adducts to the ...
Saniya Yesmin Bubli +5 more
openaire +3 more sources
Heat storage for the coupling of Waste Heat Recovery and hydrogen production in a Solid-Oxide electrolyser [PDF]
The dihydrogen molecule H2 is set to play a major role in future energy systems, both as a component of fuels or synthesis gases, and as an energy carrier for long-term electricity storage.
Fabiani Titouan +3 more
doaj +1 more source
Soluplus solutions as thermothickening materials for topical drug delivery. [PDF]
Soluplus is a pharmaceutical excipient used primarily in the manufacture of solid dispersions. The polymer also exhibits interesting rheology in aqueous solution, increasing in viscosity as the solution is warmed.
Abou Shamat, Mohamad, Cook, Michael
core +2 more sources
Synthesis and characterization of PIL/pNIPAAm hybrid hydrogels
In this study, varying amounts of NIPAAm and an ionic liquid (IL), namely 1-vinyl-3-isopropylimidazolium bromide ([ViPrIm]+[Br]−), have been used to synthesize hybrid hydrogels by radical emulsion polymerization. Amounts of 70/30%, 50/50%, 30/70%, 15/85%
Pfensig Sylvia +5 more
doaj +1 more source
Tuning the Size of Thermoresponsive Poly(N-Isopropyl Acrylamide) Grafted Silica Microgels
Core-shell microgels were synthesized via a free radical emulsion polymerization of thermoresponsive poly-(N-isopropyl acrylamide), pNipam, on the surface of silica nanoparticles. Pure pNipam microgels have a lower critical solution temperature (LCST) of
Nils Nun +5 more
doaj +1 more source
Thermally Responsive Hydrogels for Passive Temperature Regulation under Direct Sunlight
By spontaneously emitting midinfrared radiation to outer space through the atmospheric window and reflecting sunlight, daytime radiative coolers achieve notable passive cooling performance.
Dajie Xie +9 more
doaj +1 more source
Forward osmosis (FO) membrane process is expected to realize energy-saving seawater desalination. To this end, energy-saving water recovery from a draw solution (DS) and effective DS regeneration are essential.
Eiji Kamio +6 more
doaj +1 more source
A comparison between the morphology of semicrystalline polymer blends of poly(ε-caprolactone)/poly(vinyl methyl ether) and poly(ε-caprolactone)/(styrene-acrylonitrile) [PDF]
The morphology of polymer blends of poly(ε-caprolactone) (PCL) and poly(vinyl methyl ether) (PVME) is compared with that of PCL and a random copolymer of styrene and acrylonitrile (SAN).
Brinke, G. ten, +3 more
core +8 more sources
The kinetics of water transfer between the lower critical solution temperature (LCST) and upper critical solution temperature (UCST) thermoresponsive blocks in about 10 nm thin films of a diblock copolymer is monitored by in situ neutron reflectivity ...
Neng Hu +10 more
doaj +1 more source

