Results 191 to 200 of about 569,021 (235)

Iso‐Tellurazole N‐Oxides Assemble Adaptively Folded Macrocyclic Dodecamers

open access: yesChemistry – A European Journal, EarlyView.
Te…O Chalcogen bonding links twelve molecules into a ring that wraps itself around molecular guests. ABSTRACT Self‐assembled macrocyclic dodecamers were found in the crystals of new pseudo‐polymorphs of iso‐tellurazole N‐oxides. These structures are formed by molecules connected by NTe…O chalcogen bonds and are folded in a pattern that defines 89–153 ...
Jin Z. Wang   +4 more
wiley   +1 more source

Non‐Covalent Fluorine–Silica Anchoring of a Molecular Platinum(II) bis(NHC) Catalyst: Structure, Interface Control, and Hydrosilylation Activity

open access: yesChemistry – A European Journal, EarlyView.
A Pt(II) bis(NHC) complex is immobilized on mesoporous silica through directional F–Si interactions encoded in the ligand framework. Quantitative 19F{29Si} REDOR experiments and molecular dynamics simulations establish Å‐scale catalyst–support contacts and define the interfacial organization.
Alexander Bergen   +10 more
wiley   +1 more source

Catalytic Oxidation of CO and VOC in Flue Gas of Coffee Roasting Machines

open access: yesChemie Ingenieur Technik, EarlyView.
Platinum‐coated cordierite monoliths effectively oxidized CO and VOC in coffee roasting exhaust with higher Pt loadings lowering light‐off temperatures. Scaled up 90 g/ft3 catalyst in a 5 kg roaster achieved 96% CO and around 78% VOC conversion at 350°C, highlighting stable operation requires flue gas temperatures ≥350°C.
Till Hauswald   +3 more
wiley   +1 more source

Process Gas Transitions in the Steel Industry—Planning Corridors for Chemical Utilization

open access: yesChemie Ingenieur Technik, EarlyView.
Scenario‐based planning corridors link route‐ and pace‐dependent steelworks off‐gas availability (BFG, BOFG and SAFG) to a 1000 mtpd methanol demand over 2030–2060, revealing pace‐limited BFG concepts and route/site‐size limits for CO‐rich operation and motivating early CO2 tie‐ins as retrofit‐friendly safeguards.
Ömer Yildirim
wiley   +1 more source

Methanol With Increased Water Content in Internal Combustion Engines

open access: yesChemie Ingenieur Technik, EarlyView.
This study investigates the potential to improve overall Well‐to‐Wheel efficiency by using low‐purity methanol from synthesis of hydrogen and furnace gas as CO2‐source. Combustion efficiency is comparable to pure methanol, while distillation energy could be saved.
Maximilian Dobberkau   +3 more
wiley   +1 more source

Analysis of the Regulatory Framework for the CCU Technology

open access: yesChemie Ingenieur Technik, EarlyView.
ABSTRACT Carbon capture and utilisation (CCU) is increasingly considered an important technology for achieving climate neutrality within the German and European legal framework. Recent developments, particularly the Carbon Dioxide Storage and Transport Act (KSpTG), aim to enable CO2 transport infrastructure and cross‐sector carbon management systems ...
Sophie Schmengler   +2 more
wiley   +1 more source

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