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MECHANICAL PROPERTIES AND DEHYDRATION OF Li4SiO4 PEBBLES
1993A new concept of the Karlsruhe helium cooled ceramic breeder design is based on a mixed bed of small lithium orthosilicate pebbles of 0.1 - 0.2 mm diameter and 2 mm beryllium pebbles that serve as a neutron multiplier. Helium sweep gas flows through the bed and carries away the released tritium.
V. Schauer +5 more
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Study of adsorption and desorption of water on Li4SiO4
Journal of Nuclear Materials, 1989Abstract Lithium orthosilicate is one of the candidate materials for tritium breeding in a fusion reactor blanket. The release of tritium from this material depends on diffusion in the bulk and on desorption from the surface of the material which is usually covered by adsorbed water.
V. Schauer, G. Schumacher
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Feasibility Study of a New Fabrication Method for the Li4SiO4 Pebbles
Volume 5: Advanced Reactors and Fusion Technologies; Codes, Standards, Licensing, and Regulatory Issues, 2018In the past decades many R&D efforts have been spent in the development of a suitable Li4SiO4 fabrication method (e.g., melt spray process, graphite bed method, capillary-based microfluidic wet method etc.), nevertheless we are still far from an “industrial standard solution”.
Lo Frano, R. +8 more
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Fabrication of Li4SiO4 pebbles by a sol–gel technique
Fusion Engineering and Design, 2010Abstract Li4SiO4 pebbles are considered as candidate ceramic breeder materials in many blanket designs. In this work, Li4SiO4 pebbles with adequate sphericity were fabricated by a water-based sol–gel process using LiOH and SiO2 (aerosil) as the raw materials, which has not been reported for fabrication of Li4SiO4 pebbles previously. Thermal analysis,
Xiangwei Wu +3 more
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Effect of sweep gas chemistry on vaporization of Li4SiO4
Journal of Nuclear Materials, 1995Abstract Gas/solid equilibria in the system Li 4 SiO 4 D 2 D 2 O were studied by means of Knudsen effusion mass spectrometry. A Knudsen effusion mass spectrometer was modified to enable studies of reactions of hydrogen and/or water vapor with ceramic breeder materials.
Michio Yamawaki +3 more
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CO2 sorption properties of Li4SiO4 with a Li2ZrO3 coating
Journal of CO2 Utilization, 2019Abstract The application of a CO2 sorbent which releases CO2 at a lower temperature than calcium oxide is of interest in view of reducing the operating temperature or increasing the operating pressure of the super-dry reforming process. To this end, three different CO2 sorbents based on lithium orthosilicate (Li4SiO4) were prepared and characterized:
L.C. Buelens +4 more
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Effect of voltage on the AC conductivity of Li4SiO4
Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, 1985On montre qu'aux temperatures elevees, la conductivite de Li 4 SiO 4 depend de la tension appliquee, entre 50 et 1000 V.
J.M. Aceves, A.R. West
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Effect of water adsorption on tritium release from Li4SiO4
Journal of Nuclear Materials, 2013Abstract As a ceramic material proposed for tritium breeding in a fusion reactor blanket, lithium orthosilicate (Li 4 SiO 4 ) is being examined in view of the influence of water uptake on tritium release behavior. In this work, out-of-pile tritium release experiments were performed on Li 4 SiO 4 samples that were transferred and stored under ...
Chunmei Kang +7 more
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High-temperature CO2 sorption by Ca-doped Li4SiO4 sorbents
International Journal of Hydrogen Energy, 2016Abstract Ca-doped Li 4 SiO 4 (LiCa) sorbent was synthesized using a solid-state reaction method. The CO 2 sorption capacity of the sorbents was thermogravimetrically analyzed in the presence of a pure CO 2 flux. The cyclic performances of the sorbents were investigated in a twin fixed-bed reactor with absorption and desorption temperatures of 700 °
Xiaoxiang Chen +7 more
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Electrochemical formation of crystalline Li3VO4/Li4SiO4 solid solutions film
Solid State Ionics, 2008Abstract Crystalline Li 3 VO 4 /Li 4 SiO 4 (LVSO) solid solution films were prepared on Pt substrate electrochemically in absolute ethyl alcohol solution at 150 °C. XRD and Raman structure analyses indicated the presence of characteristic vibrational bands for the orthorhombic structure for the samples.
Ying Tao, Danqin Yi, Jie Li
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