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Quantitative Phase Field Modeling of Li Dendrite Growth

ECS Meeting Abstracts, 2022
Modeling and understanding dendrite growth on lithium metal anodes during charging is vital for improving battery safety. The phase field method has become an increasingly popular tool to achieve this due to its flexibility in handling complex morphologies and coupled physical processes.
Jin Zhang   +2 more
openaire   +2 more sources

Li dendrite growth and Li+ ionic mass transfer phenomenon

Journal of Electroanalytical Chemistry, 2011
Abstract Li metal dendrite growth in LiPF6–propylene carbonate (PC) electrolyte was observed in situ by a laser scanning confocal microscope (LSCM) with a metallographic microscope. The development of the electrodeposited Li dendrite length was analyzed, and compared with dendrites grown in LiClO4–PC electrolyte solution.
Kei Nishikawa   +4 more
openaire   +2 more sources

The Bonding Nature and Adhesion of Polyacrylic Acid Coating on Li-Metal for Li Dendrite Prevention

open access: yesACS Applied Materials & Interfaces, 2020
The success of polyacrylic acid (PAA) to suppress Li dendrite growth suggests that the mechanical properties of polymer-based coatings, including the modulus, toughness, and interfacial adhesion are important design criteria. However, the measurement of the adhesion of thin PAA, as well as other polymer coatings to the reactive Li-metal anode surface ...
Chi-Ta Yang   +4 more
openaire   +3 more sources

Suppressing Li Dendrite Puncture with a Hierarchical h-BN Protective Layer

ACS Applied Materials & Interfaces, 2021
Lithium metal has been perceived as an extremely attractive anode due to its superior energy density and low redox potential. However, great challenges affiliated with the operating security of Li metal batteries (LMBs) posed by growing Li dendrites hamper the widespread application of rechargeable LMBs.
Guojing Li   +8 more
openaire   +3 more sources

Li Dendrite Nucleation from First Principles Perspective

ECS Meeting Abstracts, 2019
Given the demands of modern society, current chemical energy storage needs significant improvement. Advanced battery technology research has focused on the use of Lithium metal anodes to increase performance for Li-ion, Li-sulfur and Li- air batteries.
Ethan P Kamphaus, Perla B. Balbuena
openaire   +2 more sources

Effect of nano-silica filler in polymer electrolyte on Li dendrite formation in Li/poly(ethylene oxide)–Li(CF3SO2)2N/Li

Journal of Power Sources, 2010
Abstract Lithium dendrite growth in Li/poly(ethylene oxide) (PEO)–Li(CF 3 SO 2 ) 2 N (LiTFSI)–nano-SiO 2 /Li was examined using direct in situ observation under galvanostatic conditions at 60 °C. Both the onset time of dendrite formation and the short-circuit time of the cells were extended by the addition of nano-SiO 2 filler into the polymer ...
S. Liu   +6 more
openaire   +2 more sources

Dendrite‐Free Li‐Metal Anode Enabled by Dendritic Structure

Advanced Functional Materials, 2021
AbstractThe practical application of Li‐metal anode in high‐energy rechargeable Li batteries is still hindered by the uncontrollable formation of Li dendrites. Here, a facile way is reported to stabilize Li‐metal anode by building dendrite‐like Li3Mg7 alloys enriched with Li‐containing polymers as the physical protecting layer and LiH as the Li‐ion ...
Hongyu Zhang   +4 more
openaire   +1 more source

Perspectives on Li Dendrite Penetration in Li7La3Zr2O12‐Based Solid‐State Electrolytes and Batteries: Materials, Interfaces, and Charge Transfer

Advanced Energy Materials, 2023
Garnet‐type Li7La3Zr2O12 (LLZO) solid‐state electrolytes have gained significant attention as one of the most promising electrolyte candidates for high‐energy‐density energy storage devices due to their superior stability and high ionic conductivity ...
Jie Biao   +6 more
semanticscholar   +1 more source

How Does External Pressure Shape Li Dendrites in Li Metal Batteries?

Advanced Energy Materials, 2021
AbstractHigh‐energy density lithium metal batteries have achieved great progress as next‐generation rechargeable cells. However, the huge gap in the switching from coin to pouch cells hinders their practical application. External pressure, as one discrepancy between coin and pouch cells, plays an important role in the performance of Li metal anodes ...
Xin Shen   +4 more
openaire   +1 more source

In Situ Separator Modification with an N-Rich Conjugated Microporous Polymer for the Effective Suppression of Polysulfide Shuttle and Li Dendrite Growth.

ACS Applied Materials and Interfaces, 2022
Lithium-sulfur (Li-S) batteries are very promising high-energy-density electrochemical energy storage devices, but suffer from serious Li polysulfide (LiPS) shuttle and uncontrollable Li dendrite growth.
Yanfei Yang   +4 more
semanticscholar   +1 more source

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