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A Thermally Conductive Separator for Stable Li Metal Anodes
Nano Letters, 2015Li metal anodes have attracted considerable research interest due to their low redox potential (-3.04 V vs standard hydrogen electrode) and high theoretical gravimetric capacity of 3861 mAh/g. Battery technologies using Li metal anodes have shown much higher energy density than current Li-ion batteries (LIBs) such as Li-O2 and Li-S systems.
Wei, Luo +9 more
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Unravelling the convoluted and dynamic interphasial mechanisms on Li metal anodes
Nature Nanotechnology, 2022Accurate understanding of the chemistry of solid-electrolyte interphase (SEI) is key to developing new electrolytes for high-energy batteries using lithium metal (Li0) anodes1. SEI is generally believed to be formed by the reactions between Li0 and electrolyte2,3. However, our new study shows this is not the whole story. Through synchrotron-based X-ray
Sha Tan +15 more
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Interfacial Chemistry at the Surface of Li-Metal Anodes
ECS Meeting Abstracts, 2017Efficient energy storage is essential not only for the success of renewable energies, but also for many of daily society needs including communications, electronics, and medical and biomedical applications, among others. Electrochemical cells are complex systems integrated by several materials and their corresponding interfaces whose physical ...
Perla B Balbuena +4 more
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High Concentrated Electrolytes for Li Metal Anodes
ECS Meeting Abstracts, 2017Li metal is seen as the ultimate anode for LIBs due to its extremely high theoretical energy density (3860 mAh g-1) and low negative redox potential (-3.04 V vs. standard hydrogen electrode). Making Li metal a ubiquitous anode is the key in propelling energy storage and conversion systems.
Judith Alvarado +4 more
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Molecular Understanding of Li Metal Anode
ECS Meeting AbstractsDeveloping new liquid electrolyte is a promising approach to enable the next-generation high-energy Li metal battery for wide-ranging application such as electric vehicles (EV). However, the high reactivity of Li metal interface renders it crucial to form favorable solid-electrolyte interphase (SEI), via active electrolyte decomposition, for highly ...
Weilai Yu, Yi Cui, Zhenan Bao
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Metal oxide anodes for Li-ion batteries
Ionics, 1997Recently metal oxides, especially tin oxides, have been investigated as negative electrodes in Li-ion batteries. Different compounds such as amorphous SnO2, SnO and SnSiO3 have been electrochemically cycled versus a metallic lithium electrode. In this study, the reversible capacities as well as the cycling behavior of crystalline SnO2 thin films and ...
T. Brousse +5 more
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Designing Current Collectors to Stabilize Li Metal Anodes
Advanced MaterialsAbstractRechargeable batteries employing Li metal anodes have gained increasing attention due to their high energy density. Nevertheless, low stability and reversibility of Li metal anodes severely impeded their practical applications. Designing current collectors (CCs) with reasonable structure and composition is an efficient approach to stabilizing ...
Zhimeng Hao +5 more
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Nanostructured Li Metal Anode to Inhibit Dendrite Growth in Safe Li-Metal Batteries
ECS Meeting Abstracts, 2016Li metal is considered as the “Holy Grail” of energy storage systems due to its extremely high theoretical specific capacity (3860 mAh g−1), low gravimetric density (0.59 g cm−3), and lowest negative redox potential (−3.040 V vs. standard hydrogen electrode).
Xin-Bing Cheng +5 more
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Fatigue of Li metal anode in solid-state batteries
ScienceSolid-state lithium metal batteries (SSBs) are promising for electric vehicles because of their potential to provide high energy density and enhanced safety. However, these batteries face short-circuit challenges caused by uncontrolled lithium dendrite growth during cycling.
Tengrui Wang +13 more
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Pretreatment of Li metal anode with electrolyte additive for enhancing Li cycleability
Journal of Power Sources, 2005Abstract A Li sheet electrode was galvanostatically cycled only once as a pretreatment process in a binary electrolyte, propylene carbonate (PC) with dimethyl carbonate (DMC), containing Li bis(perfluoroethylsulfonyl)imide [Li(C 2 F 5 SO 2 ) 2 N] in the presence of an additive, aluminum iodide (AlI 3 ).
Masashi Ishikawa +3 more
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