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Stable Li metal anode in a lithiophilic shuttle
Nanoscale, 2022A lithiophilic shuttle is obtained by the superposition of very thin layered copper oxide flakes, providing conjoined channels for fast and lateral Li+ transfer and stable Li plating/stripping at practical current densities and capacities.
Kailin Luo +7 more
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Interfacial challenges towards stable Li metal anode
Nano Energy, 2021Abstract Rechargeable Li metal batteries once had a glory moment in 1980s, but its development was sooner suspended for safety concerns from dendrite formation. After falling into oblivion for several decades, Li metal anode is reviving in recent years with the ever-growing demands for high energy devices. Despite great progresses have been achieved,
Zheng Luo +7 more
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Li Metal Anode with a LiZn Alloy Interlayer for Li-Metal Polymer Batteries
ECS Meeting Abstracts, 2023All-solid-state batteries (ASSB) require stable and safe Li metal anode, which needs surface preparation to increase lithium diffusion and impede the formation of dendrites. In this work, the formation of a thin LiZn layer on lithium metal using sputter deposition is reported.
Nicolas Delaporte +9 more
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Stability of Li Metal Anode in Li-S Batteries
ECS Meeting Abstracts, 2016Because of its high energy density and promising potential to revolutionize the future electric energy storage systems, the technology of Li-S batteries has attracted significant interests in recent years. With the significant progresses made on the development of cathode materials in lithium-sulfur (Li-S) batteries, the stability of anode in Li-S ...
Ruiguo Cao +5 more
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Operando Visualization of Li Metal Anodes
2022A pressing challenge facing the 21st century world is replacing fossil fuels with a competitive and renewable energy source. However, enabling widespread renewable energy sources requires improvement in the energy density of current battery technology, especially for transportation applications.
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Metal oxide anodes for Li-ion batteries
Ionics, 1997Recently metal oxides, especially tin oxides, have been investigated as negative electrodes in Li-ion batteries. Different compounds such as amorphous SnO2, SnO and SnSiO3 have been electrochemically cycled versus a metallic lithium electrode. In this study, the reversible capacities as well as the cycling behavior of crystalline SnO2 thin films and ...
T. Brousse +5 more
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High Concentrated Electrolytes for Li Metal Anodes
ECS Meeting Abstracts, 2017Li metal is seen as the ultimate anode for LIBs due to its extremely high theoretical energy density (3860 mAh g-1) and low negative redox potential (-3.04 V vs. standard hydrogen electrode). Making Li metal a ubiquitous anode is the key in propelling energy storage and conversion systems.
Judith Alvarado +4 more
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Stable Li metal anode with protected interface for high-performance Li metal batteries
Energy Storage Materials, 2018Abstract Li metal is regarded as the most attractive anode because of its high specific capacity, low reduction potential, and low density. However, low coulombic efficiency and the formation of Li dendrites cause challenges in short cycle life and safety issues, highlighting a need for an innovative design of lithium metal anode with high areal ...
Qian Wang +8 more
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Optimizing Li‐ion Solvation in Gel Polymer Electrolytes to Stabilize Li‐Metal Anode
ChemSusChem, 2023AbstractGel polymer electrolytes (GPEs) have potential as substitutes for liquid electrolytes in lithium‐metal batteries (LMBs). Their semi‐solid state also makes GPEs suitable for various applications, including wearables and flexible electronics. Here, we report the initiation of ring‐opening polymerization of 1,3‐dioxolane (DOL) by Lewis acid and ...
Kangsheng Huang +5 more
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A Thermally Conductive Separator for Stable Li Metal Anodes
Nano Letters, 2015Li metal anodes have attracted considerable research interest due to their low redox potential (-3.04 V vs standard hydrogen electrode) and high theoretical gravimetric capacity of 3861 mAh/g. Battery technologies using Li metal anodes have shown much higher energy density than current Li-ion batteries (LIBs) such as Li-O2 and Li-S systems.
Wei, Luo +9 more
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