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Disentangling Polaron Formation Pathways in Y6 by Probing Noninteracting and Interacting Chromophores via Transient Absorption Spectroscopy

open access: yesAdvanced Materials, EarlyView.
The central role of both electronically interacting and noninteracting chromophores in the photogeneration of charges has been unambiguously identified by ultrafast pump‐probe spectroscopy in thin films of the prototypical non‐fullerene acceptor Y6. Onsager‐like autoionization from higher‐energy excitations on Y6 aggregates is found to control polaron ...
Daniel Kroh   +3 more
wiley   +1 more source

Biomass DNA: An Emerging Building Block for Advanced Materials

open access: yesAdvanced Materials, EarlyView.
Biomass DNA is rapidly emerging from its traditional role as a genetic blueprint to serve as a versatile abundant, highly programmable polymeric building block. This review highlights the transformation of macroscopic bulk biomass DNA into next generation of functional materials, spanning from dynamic hydrogels, sustainable bioplastics, and high ...
Yuwei Hu, Itamar Willner, Li Niu
wiley   +1 more source

Over 95% Optical Reflectance From Structurally Modulated All‐Biopolymer Multilayers

open access: yesAdvanced Materials, EarlyView.
A new dense–porous design turns ordinary polysaccharides into highly reflective photonic multilayers. Alternating dense pectin and porous cellulose nanofiber layers create strong refractive‐index contrast without inorganic or synthetic polymers, enabling nearly perfect visible reflection, high near‐infrared reflection, broadband metallic‐like colors ...
Takaaki Kasuga   +9 more
wiley   +1 more source

Mechanically‐Driven Reconstruction of Lithium Metal for Stable All‐Solid‐State Batteries

open access: yesAdvanced Materials, EarlyView.
Mechanical reconstruction reorganizes commercial Li from surface to bulk by refining surface topography, renewing the native passivation layer, and establishing a strongly (200)‐preferred texture. Native‐passivation renewal promotes interfacial Li‐ion transport, whereas texture homogenization regulates the spatial distribution of Li flux and supports ...
Yujian Sun   +2 more
wiley   +1 more source

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