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The Liquid−Glass and Liquid−Liquid Transitions of TPP at Elevated Pressure
The Journal of Physical Chemistry B, 2008We studied the polyamorphism of the liquid triphenyl phosphite by means of broadband dielectric spectroscopy at ambient and elevated (p=500 MPa) pressures. The effect of pressure on fragility, liquid-liquid phase transition, and its kinetics is discussed in relation to the two-order-parameter model proposed by Tanaka.
Michał, Mierzwa +3 more
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Theories of Liquid-Glass Transition
Journal of Food Engineering, 1994Abstract A number of theories have been proposed to describe atomic (molecular) movements in glassy solids; their common point is that they consider collective processes when the temperature approaches T g , despite the fact that the heterogeneity of the microscopic structure of glassy materials has been implied by a number of theories.
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Fluctuations in liquids and glasses
Physica A: Statistical Mechanics and its Applications, 2002zbMATH Open Web Interface contents unavailable due to conflicting licenses.
Patashinski, Alexander Z. +1 more
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Liquid-liquid immiscibility in multicomponent glasses
Journal of Non-Crystalline Solids, 1980Abstract A general solution for calculating miscibility gaps and tie lines in multicomponent liquid mixtures is described. The calculation is based on the thermodynamic relations obtained by equating the chemical potentials of the components in the equilibrium liquid phases.
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Isoviscosity lines and the liquid-glass transition in simple liquids
Physical Review E, 2012This article presents the study of the generic behavior of viscosity of liquids based on some simple theoretical models, the soft-spheres and Lennard-Jones systems. The use of these simple models allows us to investigate in detail the viscosity behavior in a wide range of temperatures and pressures including the high-temperature-high-pressure limits ...
Yu D, Fomin, V V, Brazhkin, V N, Ryzhov
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Molecular Physics, 2016
ABSTRACTWhen liquids are cooled below their melting temperature Tm, sometimes they do not solidify immediately but remain in supercooled state up to temperatures far below the melting point. Under certain conditions, they can solidify into the form of amorphous solids without crystallizing.
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ABSTRACTWhen liquids are cooled below their melting temperature Tm, sometimes they do not solidify immediately but remain in supercooled state up to temperatures far below the melting point. Under certain conditions, they can solidify into the form of amorphous solids without crystallizing.
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Supercooled Liquids and Glasses
2010Complex systems range from supercooled liquids to glasses , to proteins, to the brain, to societies. Do these systems share properties? It is likely that they do. A hierarchically organized energy landscape and a range of motions, connecting substates, are candidates.
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Liquid–liquid transition in polymers and glass‐forming liquids
Journal of Polymer Science Part B: Polymer Physics, 1993Abstract It is shown that many simple glass‐forming liquids exhibit a phenomenon known in the area of polymer science as the liquid–liquid transition. The phenomenon manifests itself as a third‐order transition in the equilibrium liquid‐specific heat data around approximately 1.2 T g
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Liquid-Like Atoms in Dense-Packed Solid Glasses
Nature Materials, 2022Hua-Ping Zhang, Haiyang Bai, Rui Zhao
exaly