Results 91 to 100 of about 6,810 (216)

Heteroatom‐Synergistic Effect on Anchoring Polysulfides In Chalcone‐Linked Nanographene Covalent Organic Frameworks for High‐Performance Li─S Batteries

open access: yesAdvanced Science
Lithium‐sulfur (Li─S) batteries are an attractive option for future energy storage devices because they offer higher theoretical specific capacity, energy density, and cost‐effectiveness than commercial lithium‐ion batteries.
Kayaramkodath Chandran Ranjeesh   +9 more
doaj   +1 more source

A Fluorine‐Free, Low Ion Pair Electrolyte for Transition Metal‐Free and Halogen‐Free Sodium Batteries

open access: yesAdvanced Energy Materials, EarlyView.
Fluorine‐containing electrolytes dominate modern rechargeable batteries, yet the fundamental design principles for fluorine‐free systems remain largely unexplored. We demonstrate that fluorine‐free electrolyte chemistry can simultaneously achieve long cycle life, fast charging, and stable interphase formation in sodium‐ion batteries.
Dawei Xia   +7 more
wiley   +1 more source

In situ polymerization for high performance solid-state lithium-sulfur batteries

open access: yesCommunications Materials
Solid-state lithium-sulfur batteries retain high theoretical energy density and low cost of sulfur while eliminating safety issues associated with liquid electrolytes, such as leakage and flammability. More importantly, most solid electrolytes can reduce
Shengxuan Lin   +5 more
doaj   +1 more source

Internal Electric Field‐Guided, Low‐Adsorption Ferroelectric Anode Protective Layers for Sustainable Suppression of Polysulfide Side Reactions in Lithium–Sulfur Batteries

open access: yesAdvanced Energy Materials, EarlyView.
A positively polarized ferroelectric β‐pvdf layer incorporating fluorinated boron nitride nanosheets (PPFBN) establishes a strong internal field that promotes Li+ transport toward the anode while suppressing the migration of polysulfide anions. In addition, its intrinsically low polysulfide affinity helps preserve protective‐layer functionality ...
Daehun Han   +6 more
wiley   +1 more source

Synthesis of High-Sulfur-Content Resins via Inverse Vulcanization Using Dithiols and Their Application as Cathode Materials for Lithium–Sulfur Rechargeable Batteries

open access: yesElectrochem
In this study, we developed lithium–sulfur rechargeable batteries using chemically modified thermoplastic sulfur polymers as cathode active materials, aiming to effectively utilize surplus sulfur resources.
Hiroto Tominaga   +3 more
doaj   +1 more source

Multi‐modal Operando Analysis of Lithium–Sulfur Batteries: A Comparative Study on the Influence of Electrolyte Composition

open access: yesAdvanced Energy Materials, EarlyView.
The influence of different electrolytes on Lithium–sulfur batteries is investigated. Multimodal operando analysis, including Raman, UV–vis, and Impedance spectroscopy is used to study degradation mechanisms. The solubility of polysulfides in the electrolyte is crucial for battery capacity and lifetime.
Oliver Löhmann   +3 more
wiley   +1 more source

Direct visualization of complex mechanisms in lithium tellurium batteries

open access: yesNature Communications
Many studies on lithium-sulfur batteries have been conducted with respect to reaction mechanisms and performance improvements. Despite the high electronic conductivity and volumetric capacity of tellurium, research on lithium-tellurium batteries remains ...
Hyo-Yeol Choi   +10 more
doaj   +1 more source

Electrolyte Interfacial Reactivity Regulates Alloying Anode Pulverization

open access: yesAdvanced Energy Materials, EarlyView.
Electrolyte interfacial reactivity governs the degradation of micrometer‐sized alloying anodes by dictating grain refinement and SEI growth. A high‐reactivity ester‐based electrolyte drives pulverization into fine nanoparticles encapsulated by a thick SEI, forming dense electrodes, whereas a low‐reactivity ether‐based electrolyte enables porous ...
Namhyung Kim   +21 more
wiley   +1 more source

Decoupling Quasi‐Solid‐State Sulfur Conversion Mechanisms in Weakly Solvating and Locally High Concentration Electrolytes

open access: yesAdvanced Energy Materials, EarlyView.
Weakly solvating CME–TTE and localized high‐concentration G2–TTE electrolytes redirect lithium–sulfur chemistry toward quasi‐solid‐state conversion through distinct coordination environments. Molecular dynamics and multimodal electrochemical and spectroscopic measurements show that G2–TTE couples multidentate solvent coordination, anion participation ...
Boyi Pang   +12 more
wiley   +1 more source

Diffusion Coefficient and Viscosity of Methyl Viologen Electrolyte Estimation Based on a Kinetic Monte Carlo Computational Approach Coupled with the Mean Square Displacement Method

open access: yesBatteries &Supercaps, Volume 8, Issue 3, March 2025.
A novel and comprehensive 3D‐resolved kinetic Monte Carlo model coupled with mean square displacement analysis is introduced. This computational approach allows to explore, for the first time, the concentration and the state of charge effects on ionic diffusion coefficient and viscosity in methyl viologen‐based electrolytes used in organic redox flow ...
Jia Yu   +2 more
wiley   +1 more source

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