Results 31 to 40 of about 6,810 (216)

Covalent Functionalization of 2D Semiconductors: A Roadmap to Advanced Electronic Devices

open access: yesAdvanced Functional Materials, EarlyView.
This Review presents recent advances in the covalent functionalization strategies for two‐dimensional semiconductors and their implementation in modern technologies. Layered materials are modified through diverse molecular chemistries (e.g., thiols, diazonium salts, alkyl halides, and electron‐deficient species) to tailor their surface properties ...
Ramiro Quirós‐Ovies   +2 more
wiley   +1 more source

Nitride MXenes Beyond Carbides: Bridging the Gap Between Computational Prediction and Experimental Realization

open access: yesAdvanced Functional Materials, EarlyView.
Nitride MXenes remain constrained by a persistent gap between computational prediction and experimental realization. This Review identifies the thermodynamic, kinetic, and chemical barriers limiting their synthesis, critically evaluates emerging fabrication routes, and proposes a multidimensional computational‐experimental framework to accelerate the ...
Naresh Varnakavi, Masoud Soroush
wiley   +1 more source

Recent Advances in Energy Chemical Engineering of Next-Generation Lithium Batteries

open access: yesEngineering, 2018
Rechargeable lithium-ion batteries (LIBs) afford a profound impact on our modern daily life. However, LIBs are approaching the theoretical energy density, due to the inherent limitations of intercalation chemistry; thus, they cannot further satisfy the ...
Xue-Qiang Zhang   +3 more
doaj   +1 more source

A Honeycomb‐Structured CoF2‐Modified Separator Enabling High‐Performance Lithium−Sulfur Batteries

open access: yesSmall Science, 2023
Sulfur cathode materials in lithium–sulfur chemistry suffer from poor electronic conductivity and shuttle of lithium polysulfides during charging and discharging.
Wenxin Liu   +6 more
doaj   +1 more source

Photoinduced Interfacial Electronic Modulation in Fe2O3‐BiVO4 Heterostructures for Enhanced Photo‐Assisted Zn‐Air Batteries

open access: yesAdvanced Functional Materials, EarlyView.
Light irradiation activates the Fe2O3‐BiVO4 heterostructure, enabling efficient solar‐electrochemical coupling in zinc‐air batteries. The built‐in electric field drives directional charge separation, guiding photoelectrons toward oxygen reduction sites and accumulating holes for oxygen evolution, thereby reducing polarization and enhancing discharge ...
Yili Liu   +7 more
wiley   +1 more source

Rational design of sulfur-containing composites for high-performance lithium–sulfur batteries

open access: yesAPL Materials, 2019
Sulfur has received considerable attention as a cathode material for lithium—sulfur (Li—S) batteries due to its high theoretical energy density (2567 W h kg−1), high earth abundance, and environmental benignity.
Jinhua Sun   +4 more
doaj   +1 more source

Polymer Side‐Chain Electronic Effects Regulating Solvation Sheath for Low‐Temperature and High‐Voltage Lithium Metal Batteries

open access: yesAdvanced Functional Materials, EarlyView.
This work reveals the influence of polymer side‐chain electronic effects on the Li+ solvation sheath in gel polymer electrolytes. Electron‐donating side chains induce the strong Li+ coordination and FDMA‐dominated solvation, impeding Li+ desolvation, whereas electron‐withdrawing side chains weaken Li+ coordination, facilitating anion‐rich solvation and
Xianbin Wu   +7 more
wiley   +1 more source

Synergetic Interlayer in Li‐S Batteries: Polysulfide‐Impeding Effect of Conductive Carbon Cloth Supporting Topological‐Phase Bi2Se3

open access: yesChemElectroChem
The shuttle effect and sluggish sulfur conversion kinetics hamper the development of lithium–sulfur batteries. In this study, Bi2Se3 nanosheets were grown in‐situ directly on a carbon cloth and adopted as an interlayer in lithium–sulfur batteries to ...
Heng Wang   +5 more
doaj   +1 more source

Mechanistic Origins of Chemo‐Mechanical Instability and Failure in Solid‐State Lithium‐Sulfur Electrodes

open access: yesAdvanced Functional Materials, EarlyView.
Conversion‐induced sulfur expansion generates strong mechanical constraints and localized stresses within solid‐state Li‐S cathodes. Heterogeneous solid‐electrolyte confinement creates tensile strain‐energy hotspots that govern particle cracking. Larger sulfur particles accelerate fracture, while higher porosity relaxes constraint and delays damage ...
Arpan K. Sharma   +3 more
wiley   +1 more source

The effect of the heat treatment to Co-N-C derived from ZIF-67 on the electrochemical performance of lithium-sulfur battery

open access: yesMaterials Research Express, 2021
The composite of porous carbon obtained from MOFs loading sulfur has been regard as promising candidate for lithium-sulfur batteries cathode material due to the large specific surface area, high porosity, diversity of types, and designable structures ...
Xiao Cui   +6 more
doaj   +1 more source

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