Results 101 to 110 of about 2,985 (266)
Confinement‐Induced Donnan Potential Enables Sealed Hydrovoltaic Power From Microliter Water
An ultrathin MXene/cellulose nanofiber (CNF) nanochannel‐based hydrovoltaic generator produces sustained direct current (DC) from a single microliter droplet under sealed operation. Asymmetric nanochannel confinement establishes a persistent ion gradient and a confinement‐induced Donnan potential, harvesting the interfacial free energy released upon ...
Sangyun Na +10 more
wiley +1 more source
Interfacial Failure and Self‐Healing in Solid‐State Batteries
Dynamic interfacial self‐healing offers an adaptive route to mitigate coupled mechanical, chemical, and electrochemical degradation in solid‐state batteries. This review connects evolving interfacial failure mechanisms with physical‐flow, chemical‐restoration, stimuli‐responsive, and electric‐field‐assisted repair strategies, highlighting targeted self‐
Xinxin Zhu +8 more
wiley +1 more source
Interfacial charge transfer and low‐resistance interphase formation between PEO‐based polymer and Li10GeP2S12 solid electrolytes are investigated using multi‐electrode impedance spectroscopy and advanced analytical techniques such as XPS and ToF‐SIMS.
Ujjawal Sigar +6 more
wiley +1 more source
Volume changes of a solid‐state battery cell are separated into the individual contributions of anode and cathode. Simultaneously determining the “reaction volumes” of both electrodes requires a reference electrode with a pressure‐independent potential.
Mervyn Soans +5 more
wiley +1 more source
This study proposes a function‐sharing anode design to enable nonmetallic lithium insertion while maintaining intimate interfacial contact with the solid‐state electrolyte. A combination of lithium‐compatible and conformable borohydrides, highly conformable indium metal, less‐graphitized acetylene black, and a layer of highly graphitized massive ...
Keita Kurigami +3 more
wiley +1 more source
Phase Diagrams Enable Solid‐State Battery Design
Batteries are non‐equilibrium devices with inherent thermodynamic driving forces to react at interfaces, regardless of kinetics or operating conditions. Chemical potential mismatches across interfaces are dissipated via interfacial reactions. In this work, it is illustrated how phase diagrams and chemical potential maps predict degradation pathways but
Nathaniel L. Skeele, Matthias T. Agne
wiley +1 more source
CO2 sensor based on lithium ion conductor [PDF]
The engineering of junction formation and the electrode kinetics with respect to gas sensing has been investigated in electrochemical cells based on LiSiPO and Garnet electrolyte for the possibility of CO2 detection. Li2CO3 and Au paste were always used as sensing electrode and showed good agreement with Nernst equation.
openaire
An intentionally added, chemically formed LixAlSy coating stabilizes the lithium–electrolyte interface in solid‐state Li–S batteries. The layer suppresses side reactions, preserves smooth charge transfer, and improves ion transport from the start. This approach offers a practical route to more durable solid‐state batteries and a clearer understanding ...
Xinyi Wang +4 more
wiley +1 more source
A Family of Sodium Solid‐State Electrolytes Based on the NaGaxAl1‐xCl4 Solid Solution
ABSTRACT Sodium‐based metal chloride solid electrolytes are promising for sodium solid‐state batteries due to their excellent oxidation stability, which, as shown for Li halides, can coexist with high ionic conductivity. To explore cationic substitution effects, we synthesized NaGaxAl1‐xCl4 (0 ≤ x ≤ 1) via ball milling and investigated structural and ...
Hao Guo, Matteo Bianchini
wiley +1 more source
Progress on the Failure Mechanisms and Optimization Strategies on Lithium Iron Phosphate
This review centers on LiFeO4 cathodes, outlining their core advantages and performance limitations, then systematically elucidating failure mechanisms, proposing key optimization strategies, and summarizing future research directions that integrate advanced characterization with intelligent design.
Zheng‐Xin Qian +8 more
wiley +1 more source

