Results 101 to 110 of about 5,105 (214)

Molecular Design Strategies for High‐Voltage Organic Cathodes

open access: yesAdvanced Energy Materials, EarlyView.
This work proposes molecular engineering strategies for high‐voltage organic cathode materials for Li‐ion batteries: (1) increase Li‐O coordination number (CN), (2) achieve a greater increase in aromaticity upon reduction (∆Aromaticity), and (3) add an electron‐withdrawing group (EWG), through a combined experimental and computational study on reported
Sungil Hong   +8 more
wiley   +1 more source

Spatially Coupled Cl2 Confinement and Activation at Curved Ni Single‐Atom Sites for Highly Reversible Li–Cl2 Batteries

open access: yesAngewandte Chemie, EarlyView.
A robust cathode featuring curvature‐engineered Ni single‐atoms anchored within hierarchical pores effectively confines Cl2 and accelerates Cl0/Cl−1 redox kinetics. This synergistic architecture unlocks the potential of Li‐Cl2 secondary batteries with an unprecedented 1×106 mAh g−1 cumulative capacity, all‐climate resilience (–40°C to + 70°C), and 7.65
Minggang Xie   +11 more
wiley   +2 more sources

Current‐Driven Li2O Formation in Catalyst‐Free Solid‐State Li‐O2 Batteries Enabling Simultaneous High Energy and High Power

open access: yesAdvanced Energy Materials, EarlyView.
A catalyst‐free solid‐state Li‐O2 battery achieves current‐driven four‐electron Li2O formation, delivering simultaneous high‐energy and high‐power operation with 1032 Wh·kg−1 and 374 W·kg−1 in a single cell. ABSTRACT Li‐O2 batteries offer a compelling pathway toward next‐generation energy storage owing to their ultrahigh theoretical energy density ...
Shu‐Ting Ko   +9 more
wiley   +1 more source

Ionic Liquid Electrolytes for Extreme Temperature Conditions: Challenges and Perspective

open access: yesAngewandte Chemie, EarlyView.
Ionic liquids (ILs) have gained great attention as safe electrolyte components in recent years. This review elucidates the temperature effects on IL‐based electrolytes from molecular configurations, physicochemical properties, and interfacial chemistry, raises the challenges and design strategies operating at low‐ and HT, providing valuable guidance ...
En Xie   +11 more
wiley   +2 more sources

Multi-Dimensional Composite Frame as Bifunctional Catalytic Medium for Ultra-Fast Charging Lithium-Sulfur Battery. [PDF]

open access: yesNanomicro Lett, 2022
Tian S   +11 more
europepmc   +1 more source

Tracking Dynamic Sulfur Electrochemistry by Operando Techniques in Alkali Metal‐Sulfur Batteries

open access: yesAdvanced Energy Materials, EarlyView.
Dynamic sulfur electrochemistry in alkali metal‐sulfur batteries is tracked through operando spectroscopy, scattering, imaging, and modelling. This Review connects sulfur reaction pathways, polysulfide transport, electrolyte/interphase evolution, anode chemistry, and quantitative mechanistic analysis across Li‐S, Na‐S, and K‐S batteries, providing ...
Fangli Zhang   +3 more
wiley   +1 more source

Revisiting Coulombic Efficiency Paradigm: Electrolyte Additive Design for Lithium Metal Batteries

open access: yesAngewandte Chemie, EarlyView.
Coulombic efficiency (CE) is a key metric for screening advanced electrolyte formulations for rechargeable batteries. Combined with interphasial characterizations, statistical analyses of CE data uncover the synergistic interaction between fluorinated additives and salt anions, enabling more precise correlations of chemical functionalities with ...
Qixin Wang   +16 more
wiley   +2 more sources

Molecular Interfacial Regulators Enable Stable Sulfide Electrolytes for High‐Performance All‐Solid‐State Batteries

open access: yesAdvanced Energy Materials, EarlyView.
Molecular surface regulation enabled by fluoropyridines stabilizes sulfide electrolyte interfaces across both reductive and oxidative regimes. By suppressing interfacial decomposition, the modified LPSClBr enables high‐voltage operation, stable stripping/plating of Li metal, and long‐life full cells with uncoated cathodes.
Laras Fadillah   +9 more
wiley   +1 more source

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