Results 131 to 140 of about 17,906 (265)
Carboxyphenolate Coordination Frameworks for High‐Voltage Calcium Storage
Advanced Science, EarlyView.A hexaanionic carboxyphenolate coordination framework, Ca2‐M‐THBPD (M = Mg, Ca, Ba), exhibits ligand‐centered enolate‐quinonoid redox activity enabling tunable, high‐voltage Ca2+ storage (3.5 V vs Ca2+/Ca) modulated by spectator cations. The amorphous structure accommodates reversible divalent‐ion insertion, contributing to enhanced cycling stability ...
Vasudeva Rao Bakuru +12 more
wiley +1 more source
Advanced Science, EarlyView.Complex hydride anion substitution in argyrodite electrolytes has attracted attention for improving interfacial stability, yet the influence of these anions at Li metal interfaces remains unclear. This work shows that electrochemically formed BH4−‐derived interphases enable stable high‐current full‐cell cycling.
Sangho Lee +13 more
wiley +1 more source
Fluoroacetonitrile‑Based Gel Polymer Electrolytes for Fast‑Charging Lithium Metal Batteries
Advanced Science, EarlyView.A gel polymer electrolyte using fluoroacetonitrile (FAN) as the solvent and fluoroethylene carbonate (FEC) and LiNO3 as additives is proposed for fast‐charging lithium metal batteries. These additives are preferentially reduced on the lithium metal anode surface to form a stable SEI layer, effectively suppressing the reductive decomposition of FAN.
Zuoxin Yang +5 more
wiley +1 more source
Lithium anode stable in air for low-cost fabrication of a dendrite-free lithium battery. [PDF]
Nat Commun, 2019 Shen X +6 more
europepmc +1 more source
Advanced Science, EarlyView.The weakly‐solvating TFMSPyr electrolyte tailors the Li+ solvation structure by suppressing solvent coordination and promoting anion‐dominated solvation. This unique solvation environment induces preferential anion decomposition at electrode interfaces, forming robust inorganic rich S/CEI.
Bishnu P. Thapaliya +11 more
wiley +1 more source
Advanced Science, EarlyView.A mechanically adaptive polyimide interface dynamically stabilizes single‐crystal cathodes in sulfide all‐solid‐state batteries. By integrating robust chemical coordination with viscoelastic compliance, this smart coating suppresses parasitic reactions and accommodates cyclic volume expansion.
Jiatao Wu +8 more
wiley +1 more source
Impedance of Nonelectroneutral Solid Electrolyte Interphases With Nanopores: A Theoretical Model
Advanced Science, EarlyView.Physical modeling reveals that often‐neglected non‐electroneutrality and nanopores in the solid‐electrolyte interphase (SEI) govern the impedance behavior. Under nonreactive conditions, the low‐frequency constant‐phase element (CPE) phenomenon can be attributed to the nonelectroneutral local conditions in the SEI.
Chenkun Li, Jun Huang
wiley +1 more source
Advanced Science, EarlyView.A weakly solvating fluorinated cosolvent (1200ET) enables precise solvation‐power regulation in Li–S batteries, decoupling interfacial stabilization from sulfur redox kinetics. This approach suppresses polysulfide dissolution while preserving reaction kinetics, leading to a stable Li metal interface and high‐energy multilayer pouch cells, revealing a ...
Huidong Dai +9 more
wiley +1 more source